Electrolytic methods, involving a viscous electrolyte, were used to measure the diffusivity of H at temperatures of between 285 and 328K. The results (table 2) indicated that H diffused via a single-stage process at temperatures of between 285K and the melting point. No departures from Arrhenius behavior, due to trapping effects involving lattice vacancies, were found.
T.Ishikawa, R.B.McLellan: Acta Metallurgica, 1986, 34[6], 1091-5
Table 2
Diffusivity of H in Al
Temperature (K) | D (m2/s) |
285 | 7.78 x 10-15 |
288 | 1.10 x 10-14 |
293 | 1.19 x 10-14 |
295 | 1.21 x 10-14 |
296 | 1.38 x 10-14 |
297 | 4.58 x 10-14 |
304 | 3.67 x 10-14 |
309 | 2.14 x 10-14 |
315 | 8.96 x 10-14 |
328 | 1.73 x 10-13 |