A study was made of the permeation and diffusion of H (table 10) by monitoring the rate of H permeation through a liquid Al bath using manometric measurements. The diffusion coefficients were calculated from the time lag which was required in order to attain a steady state diffusion. At temperatures of between 943 and 1258K, the results could be summarised by:

P (cm2/s atm½) = 3.86 exp[-23.9(kcal/g-atom)/RT]

D (cm2/s) = 2.34 exp[-15.0(kcal/g-atom)/RT]

K.I.Vashchenko, D.F.Chernega, G.A.Remizov, O.M.Byalik: Izvestiya Vysshikh Uchebnykh Zavedenii (Tsvet. Met.), 1972, 15[1], 50-6

 

 

 

Table 10

Permeation and Diffusivity of H in Liquid Al

 

Temperature (K)

P (cm2/s atm½)

D (cm2/s)

943

1.028 x 10-5

7.586 x 10-4

960

1.31 x 10-5

8.670 x 10-4

1018

2.7 x 10-5

1.365 x 10-3

1103

6.76 x 10-5

2.438 x 10-3

1173

1.29 x 10-4

3.631 x 10-3

1228

2.02 x 10-4

4.786 x 10-3

1258

2.55 x 10-4

5.623 x 10-3