Permeation methods and mass spectroscopy were used to determine H diffusion coefficients in 3N-purity single crystals and polycrystals. The diffusion coefficients (table 88) were independent of the H concentration and could be summarised, for temperatures of between 400 and 1200, by:
D (cm2/s) = 2.0 exp[-17.8(kcal/mol)/RT]
A.P.Kakharov, V.M.Sharapov, E.I.Evko: Fiziko-Khimicheskaya Mekhanika Materialov, 1973, 9[2], 29-33
Table 88
Diffusivity of H in Mo
Temperature (C) | D (cm2/s) |
400 | 3.56 x 10-6 |
600 | 7.47 x 10-5 |
800 | 5.01 x 10-4 |
1000 | 1.84 x 10-3 |
1200 | 4.76 x 10-3 |