Permeation methods and mass spectroscopy were used to determine H diffusion coefficients in 3N-purity single crystals and polycrystals. The diffusion coefficients (table 88) were independent of the H concentration and could be summarised, for temperatures of between 400 and 1200, by:

D (cm2/s) = 2.0 exp[-17.8(kcal/mol)/RT]

A.P.Kakharov, V.M.Sharapov, E.I.Evko: Fiziko-Khimicheskaya Mekhanika Materialov, 1973, 9[2], 29-33

 

 

 

Table 88

Diffusivity of H in Mo

 

Temperature (C)

D (cm2/s)

400

3.56 x 10-6

600

7.47 x 10-5

800

5.01 x 10-4

1000

1.84 x 10-3

1200

4.76 x 10-3