Data were obtained on the permeation and diffusion of D and H in alloys which had been prepared from 3N8-purity Pd and 3N7-purity Ni. The results (tables 147 and 148) indicated that Ni additions had a relatively small effect upon diffusion and permeation.
V.A.Goltsov, V.B.Demin, P.V.Geld, G.E.Kagan: Fiziko-Khimicheskaya Mekhanika Materialov, 1971, 7[3], 56-60
Table 147
Parameters for D and H Diffusion in Pd-Ni
Ni (at%) | Isotope | Temperature (C) | Do (cm2/s) | E (kcal/g-atom) |
9.55 | H | 300-600 | 4.3 x 10-3 | 6.16 |
9.55 | D | 300-600 | 3.3 x 10-3 | 5.91 |
26.8 | H | 300-550 | 5.8 x 10-3 | 6.45 |
26.8 | D | 300-550 | 4.5 x 10-3 | 6.42 |
Table 148
Parameters for D and H Permeation in Pd-Ni
Ni (at%) | Isotope | Temperature (C) | Po (cm mm/s atm½) | E (kcal/g-atom) |
9.55 | H | 300-600 | 0.20 | 5.15 |
9.55 | D | 300-600 | 0.14 | 5.10 |
26.8 | H | 300-850 | 0.36 | 7.82 |
26.8 | D | 300-850 | 0.21 | 7.71 |