It was pointed out that there had been relatively few determinations of the diffusivity of H in this material. The apparent H diffusion coefficient could however be easily measured by using the technique of sub-surface micro-hardness profiling after cathodic hydrogen charging. The technique was used here in order to determine the diffusivity of H in stoichiometric samples, and in material which was alloyed with Cr and Ti (table 9). The diffusivities were estimated at 298K, on the basis of micro-hardness profiles, after cathodic H charging in 0.05mol/1 H2SO4 solution.

Hydrogen Diffusivity in Iron Aluminides Determined by Subscale Microhardness Profiling P.Banerjee, R.Balasubramaniam: Scripta Materialia, 1998, 39[9], 1215-9

 

 

 

Table 9

Diffusivity of H in Fe3Al-Based Alloys at 298K

 

Alloy (at%)

D (m2/s)

Fe-25A1

1.45 x 10-13

Fe-28A1-2Cr-0.15mischmetal

4.37 x 10-14

Fe-28A1-2Ti-0.15mischmetal

5.45 x 10-14

Fe-28Al-1Cr-1Ti-0.15mischmetal

4.98 x 10-14