The pressure dependence of self-diffusion in the high-temperature body-centered cubic phase of Zr was studied by using radio-tracer techniques. Activation volumes of 0.184O at 1423K and 0.213O at 1273K were obtained, where O was the atomic volume. The activation volumes for 95Nb diffusion were equal to 0.161 O at 1423K and 0.193 O at 1273K. The small activation volumes indicated a large relaxation of the vacancy. This in turn reflected the inherent weakness, of the body-centered cubic lattice, with regard to shear in the <111> direction. These results (tables 21 and 22) provided an explanation for the absence of positron trapping in group-IV transition metals.
Pressure Dependence of Self- and Solute-Diffusion in BCC Zirconium P.Knorr, J.Jun, W.Lojkowski, C.Herzig: Physical Review B, 1998, 57[1], 334-40
Table 21
Diffusivity of 95Zr in ß-Zirconium
Temperature (K) | Pressure (MPa) | D (m2/s) |
1273 | 110 | 1.438 x 10-13 |
1273 | 303 | 1.373 x 10-13 |
1273 | 601 | 1.308 x 10-13 |
1273 | 904 | 1.200 x 10-13 |
1273 | 1110 | 1.110 x 10-13 |
1273 | 1300 | 1.014 x 10-13 |
1423 | 103 | 4.055 x 10-13 |
1423 | 303 | 3.612 x 10-13 |
1423 | 605 | 3.588 x 10-13 |
1423 | 903 | 3.298 x 10-13 |
1423 | 1101 | 3.233 x 10-13 |
1423 | 1301 | 3.056 x 10-13 |
Table 22
Diffusivity of 95Nb in ß-Zirconium
Temperature (K) | Pressure (MPa) | D (m2/s) |
1273 | 110 | 4.438 x 10-14 |
1273 | 303 | 4.317 x 10-14 |
1273 | 601 | 3.957 x 10-14 |
1273 | 904 | 3.793 x 10-14 |
1273 | 1110 | 3.672 x 10-14 |
1273 | 1300 | 3.147 x 10-14 |
1423 | 103 | 1.732 x 10-13 |
1423 | 303 | 1.576 x 10-13 |
1423 | 605 | 1.534 x 10-13 |
1423 | 903 | 1.467 x 10-13 |
1423 | 1101 | 1.373 x 10-13 |
1423 | 1301 | 1.360 x 10-13 |