The pressure dependence of self-diffusion in the high-temperature body-centered cubic phase of Zr was studied by using radio-tracer techniques. Activation volumes of 0.184O at 1423K and 0.213O at 1273K were obtained, where O was the atomic volume. The activation volumes for 95Nb diffusion were equal to 0.161 O at 1423K and 0.193 O at 1273K. The small activation volumes indicated a large relaxation of the vacancy. This in turn reflected the inherent weakness, of the body-centered cubic lattice, with regard to shear in the <111> direction. These results (tables 21 and 22) provided an explanation for the absence of positron trapping in group-IV transition metals.

Pressure Dependence of Self- and Solute-Diffusion in BCC Zirconium P.Knorr, J.Jun, W.Lojkowski, C.Herzig: Physical Review B, 1998, 57[1], 334-40

 

 

 

Table 21

Diffusivity of 95Zr in ß-Zirconium

 

Temperature (K)

Pressure (MPa)

D (m2/s)

1273

110

1.438 x 10-13

1273

303

1.373 x 10-13

1273

601

1.308 x 10-13

1273

904

1.200 x 10-13

1273

1110

1.110 x 10-13

1273

1300

1.014 x 10-13

1423

103

4.055 x 10-13

1423

303

3.612 x 10-13

1423

605

3.588 x 10-13

1423

903

3.298 x 10-13

1423

1101

3.233 x 10-13

1423

1301

3.056 x 10-13

 

 

 

Table 22

Diffusivity of 95Nb in ß-Zirconium

 

Temperature (K)

Pressure (MPa)

D (m2/s)

1273

110

4.438 x 10-14

1273

303

4.317 x 10-14

1273

601

3.957 x 10-14

1273

904

3.793 x 10-14

1273

1110

3.672 x 10-14

1273

1300

3.147 x 10-14

1423

103

1.732 x 10-13

1423

303

1.576 x 10-13

1423

605

1.534 x 10-13

1423

903

1.467 x 10-13

1423

1101

1.373 x 10-13

1423

1301

1.360 x 10-13