The diffusion coefficients in the core of boundary regions were deduced from changes, in the intensity of the radiation that was emitted by atomic probes, as a function of the annealing time and temperature. The Arrhenius relationship which characterized the temperature dependence of 57Cd diffusion in the core of the so-called crystallite conjugation regions of polycrystalline W was found to be:
D (m2/s) = 2.5 x 10-10exp[-132.9(kJ/mol)/RT]
S.M.Klotsman, M.I.Kurkin, V.N.Kaigorodov, V.V.Dyakin, M.S.Dudarev: Physics of Metals and Metallography, 1996, 82[1], 67-70
Table 170
Diffusion of 57Co in W Monocrystals
Temperature (K) | D (cm2/s) |
2265 | 6.11 x 10-13 |
2144 | 1.30 x 10-13 |
2080 | 6.03 x 10-14 |
1984 | 1.23 x 10-14 |
1861 | 1.49 x 10-15 |
1773 | 3.23 x 10-16 |
1684 | 8.24 x 10-17 |
1573 | 9.56 x 10-16 |
1561 | 3.47 x 10-17 |