The dependence of tracer self-diffusion upon the isostatic pressure was studied in body-centered cubic material at pressures ranging up to 0.72GPa (table 19). Activation volumes of 55% and 45% of the atomic volume were estimated for 556 and 515K, respectively. The pressure effect upon self-diffusion in β-Tl was comparable to the situation for Na and K.

Pressure Dependence of Self-Diffusion in BCC Thallium P.Knorr, C.Herzig: Philosophical Magazine A, 1998, 77[3], 653-60

 

 

 

Table 19

Diffusivity of 204Tl in β-Thallium

 

Temperature (K)

Pressure (MPa)

D (m2/s)

515

6

2.50 x 10-13

515

156

1.76 x 10-13

515

296

1.75 x 10-13

515

439

1.19 x 10-13

515

566

7.79 x 10-14

515

718

7.39 x 10-14

556

6

9.85 x 10-13

556

155

7.83 x 10-13

556

294

4.97 x 10-13

556

456

4.07 x 10-13

556

587

3.13 x 10-13

556

714

2.26 x 10-13