Concentration Profiles for Grain Boundary Diffusion in B-Regime with Regard to the Formation of Atomic Complexes in Grain Boundary

Abstract:

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Thermodynamics of the atomic complexes formation in a grain boundary (GB) is discussed applying to AB complex. It is shown that the AB complex formation leads to the nonlinearity of segregation isothermes. Consequently, the concentration profiles for GB diffusion are nonlinear. The total (free and bound into complexes) concentration of diffusant B decreases at the given depth as the molar fraction of the complexes increases.

Info:

Periodical:

Defect and Diffusion Forum (Volumes 309-310)

Edited by:

B.S. Bokstein, A.O. Rodin and B.B. Straumal

Pages:

29-38

DOI:

10.4028/www.scientific.net/DDF.309-310.29

Citation:

V. Esin et al., "Concentration Profiles for Grain Boundary Diffusion in B-Regime with Regard to the Formation of Atomic Complexes in Grain Boundary", Defect and Diffusion Forum, Vols. 309-310, pp. 29-38, 2011

Online since:

March 2011

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Price:

$35.00

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