Synthesis of Monodispersed Inorganic-Organic Hybrid Particles from Phenyltriethoxysilane

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Preparation of monodispersed inorganic-organic hybrid particles has become one of the most attractive research topics in recent years. In this study, phenylsilsesquioxane (PhSiO3/2) particles were synthesized from phenyltriethoxysilane (PhSi(OEt)3), ethanol (EtOH), hydrochloric acid for hydrolysis and ammonia water for polycondensation by the sol-gel method. Spherical PhSiO3/2 particles were obtainable by varying the mole ratios of EtOH, H2O, HCl and NH3, to PhSi(OEt)3. The particle size was changed from 0.1 to 5.0 .m with the mole ratio. Under the optimum conditions, monodispersed particles with 1.50 .m in diameter and 0.05 of normalized standard deviation were successfully prepared.

Info:

Periodical:

Key Engineering Materials (Volumes 317-318)

Edited by:

T. Ohji, T. Sekino and K. Niihara

Pages:

677-682

DOI:

10.4028/www.scientific.net/KEM.317-318.677

Citation:

K. Shimoike et al., "Synthesis of Monodispersed Inorganic-Organic Hybrid Particles from Phenyltriethoxysilane", Key Engineering Materials, Vols. 317-318, pp. 677-682, 2006

Online since:

August 2006

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Price:

$35.00

[1] Y. Xia and G. M. Whitesides: Angrew. Chem. Int. Ed., Vol. 37 (1998), p.550.

[2] S. Shibata, T. M. Yamane K. Kamada, K. Ohta, K. Sasaki and H. Masuhara: J. Sol-Gel Sci. Tech. Vol. 8 (1997), p.959.

[3] J. Y. Choi, C. H. Kim and D. K. Kim: J. Am. Ceram. Soc. Vol. 81 (1998), p.1184.

[4] R. H. Baney, M. Itoh, A. Sakakibara and T. Suzuki: Chem. Rev. Vol. 95 (1995), p.1409.

[5] K. Katagiri, K. Hasegawa, A. Matsuda, M. Tatsumisago and T. Minami: J. Am. Ceram. Soc. Vol. 81 (1998), p.2501.

[6] A. Matsuda, T. Sasaki, T. Tanaka, M. Tatsumisago and T. Minami: J. Sol-Gel Sci. and Tech. Vol. 23 (2002), p.247.

[7] D. C. L. Vasconcelos, W. R. Campos, V. Vasconcelos, W. L. Vasconcelos: Mater. Sci. Eng. A Vol. 334 (2002), p.53.

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