Size Effects on Miscibility and Glass Transition Temperature of PS/TMPC Blend Films: a Simulation and Thermodynamic Approach


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The size dependent miscibility of binary polymer blend films of polystyrene (PS) and tetramethylbisphenol-A polycarbonate (TMPC) is studied by the molecular dynamics (MD) simulation in the way of computing Flory-Huggins interaction parameter, χ, of the blend films, which determines the blend films compatibility. It is found that the miscibility of the two polymers decreases as the film thickness D decreases. After that, the size dependent glass transition temperature Tg(w,D) of the two polymers blend films in miscible ranges are determined by computer simulation and the Fox equation where w is the weight fraction of the second component.



Key Engineering Materials (Volumes 334-335)

Edited by:

J.K. Kim, D.Z. Wo, L.M. Zhou, H.T. Huang, K.T. Lau and M. Wang




Z. M. Ao and Q. Jiang, "Size Effects on Miscibility and Glass Transition Temperature of PS/TMPC Blend Films: a Simulation and Thermodynamic Approach", Key Engineering Materials, Vols. 334-335, pp. 105-108, 2007

Online since:

March 2007




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