Hierarchically Nanostructured Porous Functional Ceramics

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We demonstrate here a self-formation phenomenon of hierarchy with multiple-scaled porosity. Macrochanneled structures, labelled as CMI-7, with openings ranging from 0.5 to 5.0 microns and wormhole-like mesoporous walls with various ceramic compositions, such as ZrO2, TiO2, Al2O3, Y2O3, ZrO2-SiO2, ZrO2-TiO2, ZrO2-Y2O3,…, aluminosilicates, aluminophosphates, silicoaluminophosphates, metallophosphates, can be prepared by just controlling the hydrolysis and polycondensation rates of the pre-selected ceramic sources. The macrochannels (funnel-like or straight) are well parallel each other and perpendicular to the tangent of the particles’ surface. These hierarchical porous ceramics can be used in catalysis, separation and for immobilization of biological molecules and even microorganisms for filtration and bioreactor applications.

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Periodical:

Key Engineering Materials (Volumes 336-338)

Edited by:

Wei Pan and Jianghong Gong

Pages:

1933-1938

DOI:

10.4028/www.scientific.net/KEM.336-338.1933

Citation:

A. Vantomme et al., "Hierarchically Nanostructured Porous Functional Ceramics", Key Engineering Materials, Vols. 336-338, pp. 1933-1938, 2007

Online since:

April 2007

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$35.00

[1] P. Yang, T. Deng, D. Zhao, et al.: Science Vol. 282 (1998), p.2244.

[2] A. Léonard, J.L. Blin and B.L. Su: Chem. Comm. (2003), p.2568.

[3] A. Léonard and B.L. Su: Chem. Comm. (2004), p.1674.

[4] A. Collins, D. Carriazo, S.A. Davis and S. Mann: Chem. Comm. (2004), p.568.

[5] Y. Amenomiya: Appl. Catal. Vol. 30 (1987), p.57.

[6] K.D. Dobson and A.J. McQuillan: Langmuir Vol. 13 (1997), p.3392.

[7] L. Shi, K.C. Tin and N.B. Wong: J. Mater. Sci. Vol. 34 (1999), p.3367.

[8] E.M. Logothetis: Chemical Sensor Technology Vol. 3 (1991), p.89.

[9] J.L. Blin, A. Léonard, L. Gigot, et al.: Angew. Chem. Int. Ed. Vol. 42 (2003), p.2872.

[10] Z.Y. Yuan, A. Vantomme, A. Léonard and B.L. Su: Chem. Comm. (2003), p.1558.

[11] A. Vantomme, Z.Y. Yuan and B.L. Su: New J. Chem. Vol. 28 (2004), p.1083.

[12] Z. Y. Yuan, T. Z. Ren and B. L. Su: Adv. Mater. Vol. 15 (2003), p.1462.

[13] T. Z. Ren, Z. Y. Yuan and B. L. Su: Colloid. Surf. A. Vol. 241 (2004), p.67.

[14] A. Imhof and D.J. Pine: Nature Vol. 389 (1997), p.948.

[15] X. Wang, J. C. Yu, C. Ho and X. Fen: Langmuir Vol. 21 (2005), p.2552.

[16] D.M. Antonelli: Microporous Mesoporous Mater. Vol. 33 (1999), p.209.

[17] O. Unal and M. Akinc: J. Am. Ceram. Soc. Vol. 78 (1996), p.805.

[18] D.J. Iiett and M. Saiful Islam: J. Chem. Soc. Faraday Trans. Vol. 891 (1993), p.3833.

[19] G.A.M. Hussein and B.C. Gates: J. Catal. Vol. 176 (1998), p.395.

[20] Z. Y. Yuan, T. Z. Ren, A. Vantomme and B. L. Su: Chem. Mater. Vol. 10 (2004), p.5096.

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