Preparation and Characterization of Ti0.6Cr0.4OxNy Nano-Sized Powder


Article Preview

Ti0.6Cr0.4OxNy bimetallic metal oxynitride nano powder was synthesized by ammonolysis of the nanosized Cr2O3/TiO2 composite powder with n(Ti):n(Cr)=6:4 at 800oC for 8 h. The precursor and the resulting oxynitride were characterized by Auger electron spectroscope (AES), X-ray diffraction analysis (XRD), electron probe microanalysis (EPMA), transmission electron microscopy (TEM), and BET surface area techniques. The result indicated that the precursor was homogenous mixture of Cr2O3 and TiO2 with high BET surface area. The as-synthesized oxynitride powder contains only Ti0.6Cr0.4OxNy with cubic structure. The BET surface area of the oxynitride powder is 37.42 m2/g and the particle size is in the range of 20~30 nm.



Key Engineering Materials (Volumes 368-372)

Edited by:

Wei Pan and Jianghong Gong




H. Z. Wang et al., "Preparation and Characterization of Ti0.6Cr0.4OxNy Nano-Sized Powder", Key Engineering Materials, Vols. 368-372, pp. 1130-1132, 2008

Online since:

February 2008




[1] F. J. Disalvo: Science. Vol. 247 (1990), p.649.

[2] A. Tyutyunnik, J. Grins and G. Svensson: Mater. Res. Bull. Vol. 33 (1998), p.1035.

[3] J. Grins, P. -O. Käll and G. Svensson: J. Mater. Chem. Vol. 5 (1995), p.571.

[4] I. D. Fawcett and K. V. Ramanujachary: Mater. Res. Bull. Vol. 32 (1997), p.1565.

[5] J. Grins: J. Europ Ceram Soc. Vol. 17 (1997), p.1819.

[6] A. El-Himri and F. Sapiña: J. Mater. Chem. Vol. 10 (2000), p.2537.

[7] X. Z. Chen and J. L. Dye: Chem. Mater. Vol. 9 (1997), p.1172.

[8] Y. G. Li and L. Gao: J. Am. Ceram. Soc. Vol. 85 (2002), p.1294.

[9] Y. G. Li and L. Gao: J. Am. Ceram. Soc. Vol. 86 (2003), p.1205.

[10] J. Vetter, H. J. Scholl and O. Knotek: Surf. Coat. Technol. Vol. 74/75 (1995), p.286.

[11] K. H. Lee and C. H. Park: Thin Solid Films, Vol. 385 (2001), p.167.

[12] P. Hones, R. Sanjinés and F. Lévy: Thin Solid Films, Vol. 332 (1998), p.240.

[13] J. J. Nainaparampil and J. S. Zabinski: Thin Solid Films, Vol. 333 (1998), p.88.