Rate Capability Fade of 18650 Li-Ion Cells

Abstract:

Article Preview

The rate capability of 18650 lithium-ion cells was studied in the paper. The experimental results showed that the reversible capacity declined to 89.5, 85.8 and 81.2% of the initial capacity after 300 cycles at discharge rate of 0.5, 1 and 2C, respectively. The XRD and SAED analysis indicated that at a high current density partial positive electrode material LiCoO2 transformed gradually from well-layered structure to rock salt cubic crystal. Upon the cycling, the degradation of cathode materials’ structure and much thicker negative film on anode electrode surface contributed to the rate capability fade.

Info:

Periodical:

Key Engineering Materials (Volumes 368-372)

Edited by:

Wei Pan and Jianghong Gong

Pages:

290-292

DOI:

10.4028/www.scientific.net/KEM.368-372.290

Citation:

F. Lian et al., "Rate Capability Fade of 18650 Li-Ion Cells", Key Engineering Materials, Vols. 368-372, pp. 290-292, 2008

Online since:

February 2008

Export:

Price:

$38.00

[1] P. Ramadass, Bala Haran, Ralph White, et al.: J. Power Sources Vol. 112 (2002), p.600.

[2] F. Lian, Z. B. Yu, et al.: High-Performance Ceramics IV (TTP, Switzerland, 2007), p.502.

[3] F. Lian, M. Wohlfahrt-Mehrens, P. Axmann et al.: Presented at The 10th Ulm Electrochemical Talks-Electrochemical Energy Storage and Conversion (Neu-Ulm, Germany, 2006).

[4] T. Osaka, S. nakade, M. Rajamäki, et al.: J. Power Sources Vol. 119-121 (2003), p.929.

[5] P. Ramadass, Bala Haran, Ralph White, et al.: J. Power Sources Vol. 112 (2002), p.614.

[6] D. Zhang, B.S. Haran and A. Durairajan: J. Power Sources Vol. 91 (2000), p.122.

[7] E.I. Santiago, A.V.C. Andrade, C.O. Paiva-Santos, et al.: Solid State Ionics Vol. 158 (2003), p.91.

[8] C. P. Grey, W.S. Yoon, J. Reed, et al.: Electrochem. Solid-State Lett. Vol. 7.

[9] (2004), p. A290. Fig. 3 single crystal selected-area diffraction pattern (with the electron beam along the.

[1] zone axis) of LiCoO2 derived from fresh (a) and 300 th cycled cells (b).

In order to see related information, you need to Login.