A Novel SiC Precursor with High Ceramic Yield: Antimony-Substituted Polysilane (APS)

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A novel SiC precursor antimony-substituted polymethylsilane (APS) is present in this paper. First, pre-APS was synthesized from polymethylsilane (PMS) and SbCl3 at room temperature. Pre-APS was a liquid mixture and could be used in PIP process without solvent. After the elemination of HCl and the crosslinking of pre-APS, the novel precursor APS with the ceramic yield 91% was prepared.

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Periodical:

Key Engineering Materials (Volumes 368-372)

Edited by:

Wei Pan and Jianghong Gong

Pages:

818-820

Citation:

L. Liu et al., "A Novel SiC Precursor with High Ceramic Yield: Antimony-Substituted Polysilane (APS)", Key Engineering Materials, Vols. 368-372, pp. 818-820, 2008

Online since:

February 2008

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$38.00

[1] T. Tanaka, N. Tamari and I. Kondoh: Jpn. J. Ceram. Soc. Vol. 104(1996), p.454.

[2] T. Mamiya,Y. Kagawa and Y. Shioji: J. Am. Ceram. Soc. Vol. 83(2000), p.433.

[3] M. Birot, J. P. Pillot and J. Dunogues: Chem. Rev. Vol. 95(1995), p.1443.

[4] K. Jian, Z. Chen, Q. Ma, H. Hu and W. Zheng: Ceram. Inte., in press.

[5] X. Cheng, , Z. Xie, J. Xiaoand Y. Song: J. Inorg. Organomet . Vol. 15(2005), p.253.

[6] R.M. Laine and A. Sellinger: US. Pat., 6, 133, 396, p. (2000).

[7] T. Iseki, M. Narisawa, K. Okamura: J. Mater. Sci. Lett. Vol. 18(1999), p.185.

[8] B. Boury, N. Bryson, G. Soula: Chem. Mater. Vol. 10(1998), p.297.

[9] F. Cao, X. Li, D. Kim: J. Organomet. Chem. Vol. 688(2003), p.125.

[10] A.M. Tsirlina, G.I. Shcherbakovaa, E.K. Florinaa, et al.: J. Eur. Ceram. Soc. Vol. 22(2002), p.2577.

[11] M. Narisawa, H. Tanno, M. Ikeda, et al.: J. Ceramic Soc. Jpn, , , Vol. 114 (2006), p.558.

[12] S. P. Gubin, A. M. Tsirlin, N. A. Popova, et al.: Inorg. Mater, , Vol. 37(2001), p.1121 Fig. 4 TGA spectra of APS crosslinked at different temperatures Fig. 5 X-ray pattern of the pyrolyzate product of APS.

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