Synthesizing Silicon Nitride Whiskers by Solvothermal and Carbothermal Methods


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Xerogel was prepared by the sol-gel method using ethyl ester orthosilicate, alcohol, carbamide and glucose with various contents as raw materials. The precursor powders were obtained after xerogel was solvothermally treated at 220oC for 2.5 h. IR analyses showed that the Si-O-Si and Si-O-NH2 bond are obtained in the precursors. XRD analyses indicated that the powders prepared by the solvothermal method are amorphous. Si3N4 powders are produced by heat-treating the precursors at 1400 oC in N2. It was proved that the synthesized powders are α–Si3N4 whiskers. With the increase of the glucose contents and the heat-treating temperature, the crystallization of Si3N4 is obviously improved.



Key Engineering Materials (Volumes 368-372)

Edited by:

Wei Pan and Jianghong Gong




G. Q. Tan et al., "Synthesizing Silicon Nitride Whiskers by Solvothermal and Carbothermal Methods", Key Engineering Materials, Vols. 368-372, pp. 868-870, 2008

Online since:

February 2008




[1] Y.P. Huang, D.H. Li, R. Wang, et al.: Fosh. Cera. Vol. 10(2003), p.13.

[2] W.L. Li, X.R. Fu, X.X. Huang, et al.: J. Cera. Vol. 4.

[11] (1983), p.469.

[3] Y.T. Qian, Y. Xie and K.B. Tang: Peri. Chin. Acad. Sci. Vol. 18.

[1] (2001), p.278.

[4] Y.J. Xiong, Y. Xie, Z.Q. Li, et al.: New. J. Chem. Vol. 18.

[28] (2004), p.214.

[5] L.G. Sheng, X.Y. Luo, H.R. Zhuang, et al.: J. Inorg. Mat. Vol. 8.

[4] (1993), p.469. Fig. 5 XRD patterns of the precursor powders prepared at 1400 o C for 5. 5h with different amounts of glucose Fig. 6 SEM image of Si3N4 powder synthesized at 1400 o C for 5. 5h with 50% excessive glucose.

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