Influence of the Surface Roughness of Plasma-Sprayed YSZ on LSM Cathode Polarization in Solid Oxide Fuel Cells


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Under SOFCs operating condition, the cathode reaction rate is determined by triple phase boundary (TPB) areas which are associated with the geometry of the interface between the cathode and the electrolyte. In this paper, YSZ electrolyte was deposited by atmospheric plasma spraying (APS). A nano-scaled lanthanum strontium manganate (LSM) cathode was prepared by sol-gel process on APS YSZ with different surface roughness to aim at increasing the TPB. The polarization curves of LSM cathode were characterized by potentiostat. The influence of the roughness of APS YSZ on the polarization of LSM cathode was investigated. It was found that the overpotential of the LSM cathode is significantly reduced with the increase of YSZ surface roughness.



Key Engineering Materials (Volumes 373-374)

Main Theme:

Edited by:

M.K. Lei, X.P. Zhu, K.W. Xu and B.S. Xu




M. Gao et al., "Influence of the Surface Roughness of Plasma-Sprayed YSZ on LSM Cathode Polarization in Solid Oxide Fuel Cells", Key Engineering Materials, Vols. 373-374, pp. 641-644, 2008

Online since:

March 2008




[1] O. Yamamoto, Electrochimica Acta, 45 (2000), 2423-2435.

[2] N. Q. Minh, J. Am. Ceram. Soc. 76 (1993), 563.

[3] M.J.L. Ostergard, C. Bagger, M. Mogensen, Electrochimica Acta, 40(1995), (1971).

[4] B.C.H. Steel, Solid State Ionics, 57(1992), 295.

[5] C. -J. Li, C. -X. Li, Y. -Z. Xing, M. Gao, G. -J. Yang, Solid State Ionics, 177(2006), 2065-(2069).

[6] S. D. Souza, S. J. Visco, L. C. Jonghe, Solid state Ionics, 98(1997), 57.

[7] E. Ivers-Tiffee, D. Herbstritt, A. Muller, A. Weber, Electrode reaction and electrochemical performance: Materials and technology development for low temperature SOFC, 41st battery symposium, Nagoya 2000, 1.

[8] D. Herbstritt, A. Weber, E. Ivers-Tiffee, Journal of European Ceramic Society, 21(2001) 1813-1816.


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