Preparation and Microwave Dielectric Properties of Ca(Sm0.5Nb0.5)O3 Ceramics

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Microstructures and microwave dielectric properties of Ca(Sm0.5Nb0.5)O3 ceramics, prepared by a conventional solid-state reaction method, were systematically investigated by varying calcining temperature, sintering temperature and cooling rate. The XRD result showed that a single Ca(Sm0.5Nb0.5)O3 phase could be synthesized at a calcining temperature of 1200 °C. Optimized combination of microwave dielectric properties of εr = 22.36, Q×f = 18030 GHz and τf = -31.2 ppm/°C was obtained for furnace-cooled Ca(Sm0.5Nb0.5)O3 ceramics sintered at 1550 °C for 4 h. However, some microcracks were found from the microstructures of the furnace-cooled specimens. Further, the Q×f value could be increased by controlling the cooling rate during the sintering process due to the disappearance of microcracks in the final material. With a cooling rate of 2 °C/min, Ca(Sm0.5Nb0.5)O3ceramics exhibited an enhanced Q×f value of 37130 GHz.

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Periodical:

Key Engineering Materials (Volumes 512-515)

Edited by:

Wei Pan and Jianghong Gong

Pages:

1198-1202

Citation:

J. M. Li and T. Qiu, "Preparation and Microwave Dielectric Properties of Ca(Sm0.5Nb0.5)O3 Ceramics", Key Engineering Materials, Vols. 512-515, pp. 1198-1202, 2012

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June 2012

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