Effect of Silica Coupling Agents on Texture Formation and Strengthening for Silica-Filled Rubber


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New finite element homogenization model with nonaffine constitutive equation of rubber is developed to study the deformation behavior of silica-filled rubber under monotonic and cyclic deformation. The obtained results clarified the effect of the volume fraction of the silica coupling agent and the networklike structure connecting the silica particles on essential physical enhancement mechanisms of deformation resistance and hysteresis loss for silica-filled rubber. The finding suggests that the material characteristics of silica-filled rubber are much more controllable than those of carbon-black-filled rubber.



Edited by:

Yeong-Maw Hwang and Cho-Pei Jiang




Y. Tomita et al., "Effect of Silica Coupling Agents on Texture Formation and Strengthening for Silica-Filled Rubber", Key Engineering Materials, Vol. 626, pp. 40-45, 2015

Online since:

August 2014




* - Corresponding Author

[1] Y. Tomita, Lu Wei, Y. Furutani, Micro- to Macroscopic Deformation Behavior of Carbon Black Filled Rubber under Monotonic and Cyclic Straining. Proc. CIMTEC 2004 Part B (2004)121-132.

DOI: https://doi.org/10.4028/0-87849-440-5.53

[2] Y. Tomita, Lu Wei, M, Naito, Yfurutani, Numerical Evaluation of Micro- to Macroscopic Mechanical Behavior of Carbon-Black-Filled Rubber. Int J Mech Sci., 48(2006)108-116.

DOI: https://doi.org/10.1016/j.ijmecsci.2005.08.009

[3] Y. Tomita, K. Azuma, M. Naito, Computational Evaluation of Strain-Rate-Dependent Deformation Behavior of Rubber and Carbon-Black-Filled Rubber under Monotonic and Cyclic Straining. Int. J. Mech. Sci., 50(2008) 856-868.

DOI: https://doi.org/10.1016/j.ijmecsci.2007.09.010

[4] M. Naito, K. Muraoka, K. Azuma, Y. Tomita, 3D modeling and simulation of micro- to macroscopic deformation behavior of filled rubber. Proc. of 5th European Conference On Constitutive Models for Rubber, (2007)127-133.

[5] M. Naito, H. Kishimoto, K. Muraoka, K. Hagita, T. Arai, Y. Shinohara, Y. Amemiya, H. Suno, S. Shingu, Structure and Mechanical Analysis of Filled Rubber, Large scale FEM Simulation of Rubber with filler by the earth simulator: Proc. of Conf. SRIJ (2007).

[6] Courtesy of SRI R&D Ltd.

[7] M. Kitamura, M. Kondou, M. Naito, Y. Tomita, Evaluation of viscoelastic deformation behavior of silica-filled rubber by molecular chain network model, Proc. JSME 57th Conference, (2008)245-246.

[8] E. M. Arruda, M. C. Boyce, A three-dimensional constitutive model for large stretch behavior of rubber materials, J. Mech. Phys. Solids, 41(1993)389-412.

[9] J. S. Bergstrom, M. C. Boyce, Constitutive modeling of the large strain time-dependent behavior of elastomers, J. Mech. Phys. Solids, 46(1998) 931-954.

[10] Y. Tomita, T. Adachi , S. Tanaka, Modelling and application of constitutive equation for glassy polymer based on nonaffine network theory, Eur. J. Mech. A/Solids, 16 (1997) 745-755.

[11] Y. Furutani, M. Naito, Lu Wei, Y. Tomita, Evaluation of Deformation Behavior of Carbon-Black-Filled Rubber under Cyclic Straining, Trans JSME 71A(2005)1109-1115.

DOI: https://doi.org/10.1299/kikaia.71.1109

[12] Y. Higa, Y. Tomita, Computational prediction of mechanical properties of nickel-based superalloy with gamma prime phase precipitates. Advance Materials and Modeling of Mechanical Behavior, III, eds. Ellyin,F. and Provan J.W., Fleming Printing Ltd., Victoria, B.C., Canada (1999).

[13] Y. Tomita, S. Nakata, T. Honma, K. Yashiro, Deformation behavior of silica-filled rubber with coupling agents under monotonic and cyclic straining, Int.J. Mech. Sci., (2014)in press.

DOI: https://doi.org/10.1016/j.ijmecsci.2013.09.030