Design of Electrophoretic Poly(2-Oxazoline)s for Hybridization with Bioactive Glass


Article Preview

We synthesised the new initiator, N-methyl bis [(nonafluorobutane) sulfonyl] imide (Nf2NMe) for 2-oxazolines derived from bis [(nonafluorobutane) sulfonyl] imide (Nf2NH). Also we compared activity of initiator of Nf2NMe with methyl triflate (TfOMe) and whether it was living polymerization. Furtheremore, not only we synthesized new initiator (Nf2NMe) for 2-oxazolines and evaluated it, but also we created a new hybride with a bioactive glass (Bioglass®45S5) by electrophoretic deposition (EPD) because poly (2-oxazoline) s have biocompatibility. Subsequently, we immersed the poly (2-oxazoline) s / bioactive glass composite film made by EPD in simulated body fluid (SBF) to form the hydroxyapatite.



Edited by:

A.R. Boccaccini, J.H. Dickerson, B. Ferrari, O. Van der Biest and T. Uchikoshi




T. Hayashi and A. Takasu, "Design of Electrophoretic Poly(2-Oxazoline)s for Hybridization with Bioactive Glass", Key Engineering Materials, Vol. 654, pp. 183-188, 2015

Online since:

July 2015




* - Corresponding Author

[1] A. Tkasu, T. Hayashi, submitted to Encyclopedia of Polymeric Nanomaterials, Cationic Ring-Opening Polymerization (2013).

[2] R. Hoogenboom, Angew. Chem. Int. Ed. 48 (2009) 7978-7994.

[3] R. Hoogenboom, Macromol. Chem. Phys. 208 (2007) 18-25.

[4] P. Goddard, L. E. Hutchinson, J . Brown, L. J. Brookman. J. Controlled Release 10 (1989) 5-16.

[5] P. Lin, C. Clash, E. M. Pearce, T. K. Kwei, M. A. Aponte, J. Polym. Sci. Part B. 26 (1988) 603-619.

[6] A. Takasu, H. Kojima, J. Polym. Sci. Part A. 48 (2010) 5953-5960.

[7] Y. Niko, G. Konishi, Macromolecules. 45 (2012) 2327–2337.

[8] M. Oshimura, T. Tang, A. Takasu, J. Polym. Sci. Part A. 49 (2011) 1210-1218.

[9] T. Moyori, T. Tang, A. Takasu, Biomacromolecules. 13 (2012) 1240-1243.

[10] T. Moyori, T. Hayashi, A. Takasu, J. Polym. Sci. Part A. 51 (2013) 3516-3522.

[11] P. Sarker, P. S. Nicholson, J. Am. Ceram. Soc. 79 (1996) 1987-(2002).

[12] J. A. Roether, A. R. Boccaccini, L. L. Hench, V. Maquet, S. Gautier, R. Jérôme Biomaterials 23 (2002) 3871-3878.

[13] O. O. Van der Biest, L. J. Vandeperre Annu. Rev. Mater. Sci. 29 (1999) 327-352.

[14] Y. Nagao, A. Takasu, A. R. Boccaccini, Macromolecules. 45 (2012) 3326–3334.

[15] T. Fukuoka, A. Takasu, RSC Adv. 4 (2014) 15983-15994.

[16] T. Honda, H. Yatsuyanagi, T. Konishi, D. Takano, Japan Patent, 2010/ 002345. (2010).

[17] H. Hussain, I. R. Green, I. Ahmed, Chem. Rev. 113 (2013) 3329-3371.

[18] T. Kokubo, H. Kushitani, S. Sakka, J. Biomed. Matter. Res. 24 (1990) 721-734.

[19] A. Gress, A. Völkel, H. Schlaad, Macromolecules. 40 (2007) 7928-7933.

[20] R. Luxenhofer, R. Jordan, Macromolecules. 39 (2006) 3509-3516.

Fetching data from Crossref.
This may take some time to load.