Preparation of Cobalt Phthalocyanine Supported Mg-Al Hydrotalcite and its Catalytic Activity for Degradation of Methylene Blue
A novel supported catalyst is prepared through immobilization of water soluble phthalocyanine, which is synthesized by modifying tetraminophthalocyanine with cyanuric chloride, onto the supporting material Mg-Al hydrotalcite via co-precipitation method. The structure of the catalyst is characterized by infrared spectroscopy instrument (FT-IR) and X-ray diffractometer. Catalytic activity is examined through comparative experiments. The results show that it exhibits high catalytic activity for degradation of methylene blue (MB) in the presence of H2O2, the remaining rate of MB is 12.02% after 6 h. The reaction process conforms to the equation of pseudo-first-order kinetics, and the correlation coefficient R2> 0.99. The recycling tests for five times are also carried out and prove its reusability in catalytic application.
Katsuyuki Kida and Koshiro Mizobe
M. X. Qian et al., "Preparation of Cobalt Phthalocyanine Supported Mg-Al Hydrotalcite and its Catalytic Activity for Degradation of Methylene Blue", Key Engineering Materials, Vol. 748, pp. 433-437, 2017