Non-Traditional Cement and Concrete

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Authors: Ionna Papayianni, Stavroula Konopisi, Fotini Kesikidou
Abstract: In this paper, the physico-mechanical properties of alkali-activated mortars (CF/S) containing calcareous fly ash (CF) from the combustion of lignite and ladle furnace slag (S) from the steelmaking process as binders as well as sand and glass cullet as inert material have been studied. The constituents were mixed with the alkaline activator (NaOH:Na2SiO3 was 1:1). The binders and aggregates were used in a ratio 1:3 while a part of sand was replaced by glass aggregates (60%). The specimens (dimensions 40x40x160 mm) of alkali-activated mixtures CF/S: 100/0, 80/20 and 50/50 were cured at 25 °C for 2 days and then were placed in humid environment (95±5 % RH, 25 °C). Then the mechanical strength and porosity at 7-d, 28-d and 90-d age were measured. All of the CF/S specimens exhibited compressive strength around 15 MPa at 28 days. After the 28-d age the specimens of CF/S mortars were exposed to wetting/drying and freeze/thaw cycles to have an estimation of durability of alkali-activated CF/S mortars and compared to the Portland I42.5 cement mortars (PC) of high strength 43 MPa. Mass loss of specimens was measured by weighing them. The results showed that alkali-activated CF/S mortars appear to have similar or slight lower behavior to wetting/drying and freeze/thaw cycles compared to net cement mortars.
Authors: Łukasz Kotwica, Ewa Kapeluszna, Piotr Stępień, Jan Deja, Mirja Illikainen, Łukasz Gołek
Abstract: Influence of sodium sulphide on properties of sodium hydroxide activated ground granulated blast furnace slag was investigated. Properties of both fresh (cone flow, density) as well as hardened (compressive strength) mortars were determined. Early hydration of pastes was investigated using conducting calorimetry. Results showed, that introduction of sodium sulphide to caustic soda activated slag only slightly influence the course of hydration process. Early strength is increased by about 10%. In later periods strength is virtually not affected by the presence of sodium sulphide. Those observations are confirmed by calorimetric results. Presence of sodium sulphide causes slight decrease in consistency of mortars. Colour of mortars is also affected by the presence of sulphides. It is more darker and it is most probably due to the reducing properties of sulphide ions. Results of model investigations on precipitated C-S-H phase showed, that presence of sulphides results in increased main basal spacing of C-S-H phase as determined by XRD.
Authors: Ionna Papayianni, Fotini Kesikidou, Stavroula Konopisi
Abstract: Over the last years, the increasing need of cost saving and environmental protection has led to finding alternative methods and materials in construction. One of these methods is the alkali-activation, which can transform alumino-silicate binders, like siliceous fly ashes, blast furnace slags, into useful materials. On the other hand, little focus has been given to study the potential uses of high calcium fly ashes (HCFAs), which are also produced in Europe and constitute the half of total fly ash output.In this paper, a calcareous fly ash (F) from Agios Demetrios power plant in Greece was studied in combination with different alumino-silicate materials such as pozzolan, diatomite and brick dust in order to improve their physico-mechanical characteristics. Pastes were mixed with an alkaline activator, which consists of a sodium silicate solution and sodium hydroxide solution 10M. The weight ratio of NaOH:Na2SiO3 was 1:1. At the fresh state, setting time of the mixture was measured after mixing. Prismatic specimens were matured at different temperature conditions (25°C for 2 days and 65°C for 2 days). The samples were tested under flexural and compressive strength at the ages of 2, 7 and 28 days. Volume deformation and open porosity were also determined.
Authors: Jacek Domski, Jacek Katzer
Abstract: The paper presents a research programme focused on steel fibre reinforced concrete (SFRC) based on waste ceramic aggregate (WCA) prepared from debris. The matrix was reinforced by steel fibre from 0.5% to 1.5% (by volume). Flexural tests were performed using a limit of proportionality (LOP) method and a procedure based on optical measurements with the help of Digital Image Correlation (DIC) System. Residual strengths were calculated and flexural strength classes were assigned. Conclusions concerning both properties of SFRC based on WCA and feasibility of using DIC system for testing SFRC were drawn.
Authors: Stanislav Seitl, Petr Miarka, Jan Klusák, Jacek Domski, Jacek Katzer, Hana Šimonová, Zbyněk Keršner
Abstract: Concrete used in civil structures is usually made on cement-based matrix and natural aggregates (such as sand, gravel, crushed stone, etc.). Ceramic waste aggregate is considered as a perspective replacement of a part of natural aggregate in modern environmentally oriented building material. Concrete with natural aggregate partially replaced by ceramic waste aggregate usually show different mechanical characteristics than ordinary concrete. This paper introduces the pilot study of fatigue parameters of six concrete mixtures with various amount of ceramic waste. The experimentally obtain results are compared and discussed.
Authors: Martin Sedlmajer, Jiří Zach, Jitka Hroudova
Abstract: The hydration of cement is a very intricate process. A great amount of heat is generated during the reaction, which requires close monitoring especially in large concrete members. Modified cement pastes are simpler systems and can be easily used to observe the effect of plasticizing admixtures on the development of temperatures during cement hydration as well as its rheology and mechanical properties. Knowledge of the development of hydration temperatures can be of assistance in deliberate regulation of cement hydration and the generation of hydration heat. The paper describes what influence different amounts of different plasticizers have on the properties of cement pastes, with added focus on the development of their hydration temperatures, rheology and compressive strength.
Authors: Vlastimil Bílek, David Pytlík, Marketa Bambuchova
Abstract: Use a ternary binder for production of a high performance concrete with a compressive strengths between 120 and 170 MPa is presented. The water to binder ratio of the concrete is 0.225 and the binder is composed of Ordinary Portland Cement (OPC), condensed silica fume (CSF), ground limestone (L), fly ash (FA) and metakaoline (MK). The dosage of (M + CSF) is kept at a constant level for a better workability of fresh concrete. Different workability, flexural and compressive strengths were obtained for concretes with a constant cement and a metakaoline dosage, and for a constant dosage (FA + L) but a different ratio FA / L. An optimum composition was found and concretes for other tests were designed using this composition.
Authors: Martina Šomodíková, Břetislav Teplý, Dita Vořechovská
Abstract: The assessment of service life of a structure can be performed via mathematical modelling – either analytical or numerical and it can be viewed as a necessary pre-requisite for life-cycle engineering decisions. Many works concerning the modelling and testing of degradation effects for engineering systems are reported in the literature. The present paper discusses the degradation modelling of reinforced concrete structures and concentrates on the damage they sustain due to chloride ingress, namely a special aspect: the influence of statistical correlation among input variables on the reliability.
Authors: Pavel Šiler, Iva Kolářová, Jiří Másilko, Radoslav Novotný, Tomáš Opravil
Abstract: Concrete is still the most commonly used building material. The main component of concrete is Portland cement. Due to increasing use of secondary products containing zinc, the amount of zinc in the clinker or in the secondary raw materials is increasing in recent years. Portland clinker can gain zinc from solid waste or tires which are widely used as a fuel for a burning in rotary kiln. In the case of secondary raw materials, zinc may be present in the primary material, where the manufacturing process leads to its removal and concentrating to "waste" which is used in the cement industry. The biggest problem with cement doped with zinc is the retardation of hydration and decreasing of mechanical properties. The main aim of this work is describing and evaluation of zinc effect on the course of Portland cement hydration.
Authors: Hanaa Y. Ghorab, Hossam E.H. Ahmed, Ali S. Shanour, Hamdy M.A. Wahdan
Abstract: The effect of calcined clays of the swelling type, on the strength and expansion behavior of Portland limestone cement is studied at 5°C. Local clays were thermally activated by burning one hour at 900 °C and were ground to a Blaine of 2842 (cm2/g). The pozzolanic reactivity of the activated clays was defined chemically and according to ASTM C311/C311M-13. Portland limestone cement was prepared by replacing 30% CEM I 42.5 N by limestone powder. Pozzolanic cements were prepared by replacing 10 and 20% of the limestone powder by calcined clays, the mixes were used to replace 30% of CEM I. Mortars specimens pre-cured for 28-day long as well as for a short period of one day, were immersed in sulfate solutions at 5°C for time up to 90 days. The compressive strength and length change were measured for the samples.The results show that replacement of limestone with calcined clays improves the compressive strength and the expansion of Portland limestone cement mortars in water and sulfate solutions. Ettringite was detected in the expanded mortars and no thaumasite formed. The results are interpreted in terms of the mechanism of thaumasite formation.

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