A Nonaffine Molecular Chain Network Model for Elastomeric Gel

Abstract:

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Submerged in a solvent-containing environment and subject to applied forces, a nonaffine molecular chain network absorbs the solvent and deforms, forming an elastomeric gel. The Helmholtz free energy of the gel is separated into the contribution due to stretching the nonaffine molecular chain network and that due to mixing the polymer and the solvent. The effect of the nonaffine movement of the molecular chain on the deformation behavior of the gel is discussed.

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Edited by:

Luis Rodríguez-Tembleque, Jaime Domínguez and Ferri M.H. Aliabadi

Pages:

203-209

Citation:

I. Riku et al., "A Nonaffine Molecular Chain Network Model for Elastomeric Gel", Key Engineering Materials, Vol. 774, pp. 203-209, 2018

Online since:

August 2018

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$38.00

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[1] Z. Liu and P. Clavert: Adv. Mater. Vol. 12 (2000), p.288.

[2] D.J. Beebe, J.S. Moore, J.M. Bauer, Q. Yu, R.H. Liu, C. Devadoss and B.H. Jo: Nature Vol. 404 (2000), p.588.

[3] S.Q. Cai, Y.C. Lou, P. Ganguly, A. Robisson and Z.G. Suo: J. Appl. Phys. Vol. 107 (2010), p.103535.

[4] W. Hong, X.H. Zhao, J.X. Zhou and Z.G. Suo: J. Mech. Phys. Solids Vol. 56 (2008), p.1779.

[5] Y.H. An, F.J. Solis and H.Q. Jiang: J. Mech. Phys. Solids Vol. 58 (2010), p. (2083).

[6] C.Y. Hui and V. Muralidharan: J. Chem. Phys. Vol. 123 (2005), p.154905.

[7] S.A. Chester and L. Anand: J. Mech. Phys. Solids Vol. 58 (2010), p.1879.

[8] P.J. Flory and J. Rehner: J. Chem. Phys. Vol. 11 (1943), p.521.

[9] S.Q. Cai and Z.G. Suo: EPL Vol. 97 (2012), p.34009.

[10] T. Sakai: Physics of Polymer Gels (University of Tokyo Press, 2017).

[11] S.P. Obukhov, M. Rubinstein and R.H. Colby: Macromelecules Vol. 27 (1994), p.3191.

[12] I. Riku and K. Mimura: Int. J. Mechanical Sci. Vol. 52 (2010), p.287.

[13] M. Doi and S.F. Edwards: The Theory of Polymer Dynamics (Oxford University Press, 1986).

[14] K. Konda, K. Urayama and T. Takigawa: Macromolecules Vol. 44 (2011), p.3000.

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