Effect of Various Solid Loadings in Producing Silica-Nickel Oxide (SiO2- NiO) Foams

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Porous ceramic body is broadly utilized in the engineering discipline in this globalization era especially in the industrial applications. This is due to the advantages of one of the ceramic foams characteristics that can exhibit highly open pore and have a good interconnectivity. At the present study, the formation of Silica-Nickel oxide (SiO2-NiO) foams was developed by using the replication method with various solid loadings of 20wt. %, 25wt. %, 30wt. %, 35wt. % by adding a fixed amount of 5wt. % composition of Nickel Oxide (NiO) and sintered at a temperature of 1250°C. The Polyethylene Glycol (PEG) and Carboxymethyl Cellulose (CMC) as the binders to bind the particles and as thickening agent for the slurries formation. The cylindrical shape polyurethane acts as a template of the SiO2-NiO foams. The properties of physical and mechanical of the SiO2-NiO foams are being characterized through the morphology analysis via the Scanning Electron Microscope (SEM). Bulk density and apparent porosity tests are determined by adapting the Archimedes Principles. The compressive test has been carried out to identify the compressive strength of SiO2-NiO foams. The results obtained during the morphology analysis show the size of the pores appeared differently between the ranges of 268.81µm to 516.17µm. The result of the density and porosity of the porous SiO2-NiO foams recorded results between the ranges of 0.452g/cm3 to 0.775g/cm3 and 68.5% to 81.2%. This indicates that the variable of solid loading reveals the effect on the properties of the SiO2-NiO foams. Thus, the increasing of the solid loading will decrease the average size of the pores. However, with the decreasing of the average size of the pores will increase the density and the compressive strength of SiO2-NiO foams.

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Edited by:

Al Emran Ismail, Muhamad Zaini Yunos, Reazul Haq Abdul Haq and Said Ahmad

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50-56

Citation:

N. A. Nazaruddin et al., "Effect of Various Solid Loadings in Producing Silica-Nickel Oxide (SiO2- NiO) Foams", Key Engineering Materials, Vol. 791, pp. 50-56, 2018

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November 2018

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[1] J. Luyten, S. Mullens, J. Cooymans, A. M. De Wilde, and I. Thijs, New Processing Techniques of Ceramic Foams, Advanced Engineering Materials. 5 (2003) 715–718.

DOI: https://doi.org/10.1002/adem.200300381

[2] P. Colombo, Conventional and novel processing methods for cellular ceramics, Phil. Trans. R. Soc. A. 364 (2006) 109–124.

[3] R. Narayan, P. Colombo, S. Widjaja, and D. Singh, Advances in Bioceramics and Porous Ceramics IV, Wiley, 2011, pp.157-224.

[4] S. M. Sharif, Z. a Ahmad, and M. R. Othman, Tubular Ceramic Foam Via Polymeric Sponge Method, International Journal of Scientific & Technology Research. 2 (2013) 282–284.

[5] U. T. Gonzenbach, A. R. Studart, E. Tervoort, and L. J. Gauckler, Macroporous Ceramics from Particle-Stabilized Wet Foams, J.Am. Ceram. Soc. 90 (2007) 16–22.

DOI: https://doi.org/10.1111/j.1551-2916.2006.01328.x

[6] S. Dhara and P. Bhargava, A simple direct casting route to ceramic foams, J. Am. Ceram. Soc. 50 (2003) 1645–1650.

DOI: https://doi.org/10.1111/j.1151-2916.2003.tb03534.x

[7] Y. Li, W. Cao, L. Gong, R. Zhang, and X. Cheng, Properties of highly porous cordierite ceramic obtained by direct foaming and gelcasting method, Ceramics - Silikaty. 60 (2016) 91–98.

DOI: https://doi.org/10.13168/cs.2016.0014

[8] C. Real, M. D. Alcalá, and J. M. Criado, Preparation of silica from rice husks, J. Am. Ceram. Soc, 79 (1996) 2012–(2016).

[9] A. Ananthi, D. Geetha, and P. S. Ramesh, Preparation and Characterization of Silica Material from Rice Husk Ash – An Economically Viable Method, Chemistry and Materials Research. 8 (2016) 1–7.

[10] N. Yalçin and V. Sevinç, Studies on silica obtained from rice husk, Ceramics International. 27 (2001) 219–224.

DOI: https://doi.org/10.1016/s0272-8842(00)00068-7

[11] Y. Shen, P. Zhao, and Q. Shao, Porous silica and carbon derived materials from rice husk pyrolysis char, Microporous and Mesoporous Materials. 188 (2014) 46–76.

DOI: https://doi.org/10.1016/j.micromeso.2014.01.005

[12] J. Zhang and F. Li, Applied Catalysis B : Environmental Coke-resistant Ni @ SiO 2 catalyst for dry reforming of methane. Applied Catalysis B, Environmental. 176 (2015) 513–521.

DOI: https://doi.org/10.1016/j.apcatb.2015.04.039

[13] F. Huang, R. Wang, C. Yang, H. Driss, W. Chu, and H. Zhang, Catalytic performances of Ni/mesoporous SiO2 catalysts for dry reforming of methane to hydrogen, Journal of Energy Chemistry. 25 (2016) 709–719.

DOI: https://doi.org/10.1016/j.jechem.2016.03.004

[14] N. Pegios, G. Schroer, K. Rahimi, R. Palkovits, and K. Simeonov, Design of modular Ni-foam based catalysts for dry reforming of methane, Catal. Sci. Technol. 6 (2016) 6372–6380.

DOI: https://doi.org/10.1039/c6cy00282j

[15] F. Mat Noor, K. R. Jamaluddin, S. Ahmad, R. Ibrahim, and N. I. Mad Rosip, Development and Characterization of SS316L Foam Prepared by Powder Metallurgy Route, Applied Mechanics and Materials. 534, (2014) 31–37.

DOI: https://doi.org/10.4028/www.scientific.net/amm.534.31

[16] C. Voigt, C. G. Aneziris, and J. Hubálková, Rheological characterization of slurries for the preparation of alumina foams via replica technique, J. Am. Ceram. Soc. 98 (2015) 1460–1463.

DOI: https://doi.org/10.1111/jace.13522

[17] M. A. A. Muhamad Nor, L. C. Hong, Z. Arifin Ahmad, and H. Md Akil, Preparation and characterization of ceramic foam produced via polymeric foam replication method, Journal of Materials Processing Technology. 207 (2008) 235–239.

DOI: https://doi.org/10.1016/j.jmatprotec.2007.12.099

[18] M. A. A. M. Nor, H. M. Akil, and Z. A. Ahmad, The effect of polymeric template density and solid loading on the properties of ceramic foam, Science of Sintering. 41 (2009) 319–327.

DOI: https://doi.org/10.2298/sos0903319n

[19] A. B. N. M. S. Sharmiwati, R. M. Mizan, Preparation And Characterization Of Ceramic Sponge For Water Filter, International Journal of Scientific & Technology Research. 3 (2014) 103–106, (2014).

[20] J. P. Li, S. H. Li, K. de Groot, and P. Layrolle, Preparation and Characterization of Porous Titanium, Key Engineering Materials. 218 (2002) 51–54.

DOI: https://doi.org/10.4028/www.scientific.net/kem.218-220.51

[21] Y. C. G. Hamimah Abd. Rahman, Preparation of Ceramic Foam By Simple Casting Process, International Conference on Engineering and Environment 2007 (ICEE 2007). 2–5.