Compatibilizer Effect of Grafted Glycidyl Methacrylate on EPDM/Organoclay Nanocomposites


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The nanocomposite formation in ethylene/propylene/diene rubber (EPDM) mixed with montmorillonite modified with octadecylamine (MMT-ODA) was investigated. The rubber formulation used proved to be critical for the final materials’ properties. The combined action of the curatives and glycidyl methacrylate (GMA), which was grafted on the EPDM, resulted in better intercalation and enhanced mechanical behavior of the rubber nanocomposites.



Edited by:

Jaroslav Pokluda




K.G. Gatos et al., "Compatibilizer Effect of Grafted Glycidyl Methacrylate on EPDM/Organoclay Nanocomposites", Materials Science Forum, Vol. 482, pp. 347-350, 2005

Online since:

April 2005




[1] P.C. LeBaron, Zh. Wang and Th.J. Pinnavaia: Appl. Clay Sci. Vol. 15 (1999), p.11.

[2] S.S. Ray and M. Okamoto: Prog. Polym. Sci. Vol. 28 (2003), p.1539.

[3] A. Mousa and J. Karger-Kocsis: Macromol. Mater. Eng. Vol. 286 (2001), p.260.

[4] F. Schön, R. Thomann and W. Gronski: Macromol. Symp. Vol. 189 (2002), p.105.

[5] Ch. Nah, H.J. Ryu, S.H. Han, J.M. Rhee and M.H. Lee: Polym. Int. Vol. 50 (2001), p.1265.

[6] J.T. Kim, T.S. Oh and D.H. Lee: Polym. Int. Vol. 52 (2003), p.1058.

[7] S. Varghese, J. Karger-Kocsis and K.G. Gatos: Polymer Vol. 44 (2003), p.3977.

[8] W. Hofmann: Rubber Technology Handbook (Hanser, Munich 1994), p.100.

[9] A. Usuki, A. Tukigase and M. Kato: Polymer Vol. 43 (2002), p.2185.

[10] Y.W. Chang, Y. Yang, S. Ryu and Ch. Nah: Polym. Int. Vol. 51 (2002), p.319.

[11] H. Zheng, Y. Zhang, Z. Peng and Y. Zhang: Polym. Test Vol. 23 (2004), p.217.

[12] H. Zheng, Y. Zhang, Z. Peng and Y. Zhang: J. Appl. Polym. Sci. Vol. 92 (2004), p.638.

[13] N. Papke and J. Karger-Kocsis: J. Appl. Polym. Sci. Vol. 74 (1999), p.2616.

[14] W.S. Chow, Z.A. Mohd Ishak, J. Karger-Kocsis, A.A. Apostolov and U.S. Ishiaku: Polymer Vol. 44 (2003), p.7427.

[15] K.G. Gatos, R. Thomann and J. Karger-Kocsis: Polym. Int. Vol. 53 (2004), p.1191.