Examinations of Cross-Linked Polyvinylpyridine in Open Reactor


Article Preview

Macroporous cross-linked copolymer of 4-vinylpyridine and 25% (4:1) divinylbenzene is analyzed under open conditions, that is in a continuous well-stirred tank reactor (CSTR). With this aim the appropriate bifurcation diagram is found and the behavior of the system with and without polymer in the vicinity of the bifurcation point is used for the polymer examinations. Two different granulations of polymer are considered. Moreover, some physicochemical characteristics of the polymer, such as specific surface area, skeletal and particle density, are determined.



Edited by:

Dragan P. Uskokovic, Slobodan K. Milonjic, Djan I. Rakovic






M. Milošević et al., "Examinations of Cross-Linked Polyvinylpyridine in Open Reactor", Materials Science Forum, Vol. 494, pp. 369-374, 2005

Online since:

September 2005




[1] G.L. Goe, C.R. Marston, E.F.V. Scriven and E.E. Sowers: in D.W. Blackburn (Editor), Catalysis of Organic Reactions (Marcel Dekker, New York, 1990) p.275.

[2] J. Ekerdt: The Role of Substrate Transport in Catalyst Activity, in W.T. Ford, Ed., Polymeric Reagents and Catalysts (American Chemical Society, Washington DC, 1986) p.68.

[3] R.L. Albright: Basic Principles of Catalysis by Functionalized Porous Organic Polymers: Theoretical Concepts and Considerations, in A.B. Stiles, Ed., Catalysts Supports and Supported Catalysts, (Butterworths, London, 1987) p.159.

[4] M.C. Maillard-Terrier, C. Caze: European Polymer Journal, 20 (1984), p.113.

[5] B.P. Belousov: A Periodic Reaction and Its Mechanism, in Zbornik Referatov po Radiatsionnni Meditsine, (Medgiz, Moscow, 1959) p.145.

[6] W.C. Bray: J. Am. Chem. Soc., 43 (1921), p.1262.

[7] W.C. Bray, H.A. Liebhafsky: J. Am. Chem. Soc., 53 (1931), p.38.

[8] J. Maselko, J.S. Reckley, K. Showalter: J. Phys. Chem., 93 (1989) p.2774.

[9] A. Lazar, Z. Noszticzius, H.D. Forsterling, Z. Nagy-Ungvarai: Physica D: Nonlinear Phenomena, 84 (1995) p.112.

DOI: 10.1016/0167-2789(95)00009-s

[10] R. Yoshida, T. Sakai, S. Ito, T. Yamaguchi: J. Am. Chem. Soc., 124 (2002), p.8095.

[11] R. Jiménez-Prieto, M. Silva and D. Pérez-Bendito: Anal. Chem., 67 (1995), p.729.

[12] V. Vukojević, N. Pejić, D. Stanisavljev, S. Anić, Lj. Kolar-Anić: Analyst, 124 (1999), p.147.

DOI: 10.1039/a807608a

[13] A. Terlecki-Baričević, Ž. Čupić, S. Anić, Lj. Kolar-Anić, S. Mitrovski and S. Ivanović: J. Serb. Chem. Soc., 60 (1995), p.969.

[14] Ž. Čupić, S. Anić, A. Terlecki-Baričević, Lj. Kolar-Anić: React. Kinet. Catal. Lett., 54 (1995), pp.43-49.

DOI: 10.1007/bf02071179

[15] N. Pejić, Ž. Čupić, S. Anić, V. Vukojević, Lj. Kolar-Anić: Science of Sintering, 33 (2001) p.107.

[16] N. Pejić, S. Anić, V. Kuntić, V. Vukojević and Lj. Kolar-Anić: Microchim. Acta 143 (2003) p.261.

DOI: 10.1007/s00604-003-0071-8

In order to see related information, you need to Login.