Influence of Additive Type on Densification and Phase Transformation of Seeded Si3N4


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This paper deals with densification and a®b phase transformation of Si3N4, with a constant b-Si3N4 seeds concentration regarding sintering temperature and different additive types. The seeds of b-Si3N4 were obtained by sintering of silicon nitride in a-form and additive mixture consisting of Y2O3 and SiO2. Two different Si3N4/additive mixtures (Y2O3 + Al2O3 and CeO2) containing constant amount of seeds were prepared and tested. Characterization of sintered samples involved phase analysis by X−ray diffraction and density measurements. The results indicated that in the presence of yttria-alumina mixture both the phase transformation and the densification were enhanced as compared to samples containing only CeO2 as a sintering additive. The reasons for observed behavior are discussed in detail.



Edited by:

Dragan P. Uskokovic, Slobodan K. Milonjic, Djan I. Rakovic




A. Vučković et al., "Influence of Additive Type on Densification and Phase Transformation of Seeded Si3N4", Materials Science Forum, Vol. 494, pp. 429-434, 2005

Online since:

September 2005




[1] G. Petzow, M. Hermman, Silicon Nitride Ceramics, Structure and Bonding, Springer - Verlag Berlin Heidelberg, Vol. 80 (2002), p.51.

[2] P. Sajgalik, J. Dusza and M. Hoffman, J. Am. Ceram. Soc., 78 (10) (1995), p.2619.

[3] M. Mitomo, N. Hirosaki and H. Hirotsuru, MRS Billetin, February (1995), p.38.

[4] K. Watari, J. Ceram. Sci. Jpn., 109 (2001), p.57.

[5] A. Vuckovic and S. Boskovic, J. Serb. Chem. Soc., 69 (1) (2003), p.59.

[6] C.P. Gazzara, D.R. Messier, J. Am. Ceram. Soc. 78 (1977), p.1076.

[7] S. Bošković, Journal of Materials Science 25 (1990), p.1513.

[8] G. Z. Cao, Z. K. Huang, X. R. Fu, and D. S. Yan, Int. J. High Technol. Ceram., 1(2) (1985), p.119.

[9] Z. K. Huang, P. Greil and G. Petzow, Ceram. Inter. 10 (1) (1984), p.14.

[10] E. F. Bertaut, J. Mareschal and C R. Hebd, Seances Acad. Ci., 44 (1963), p.867.

[11] S. Bošković, M. Dukić, S. Zec and E. Kostić, Science of Sintering 24 (2) (1992), p.125.

[12] L. K L. Falk and G. L. Dunlop, J. Mat. Sci. 22 (1987), p.4369.

[13] L. A. Pierce, D. M. Mieskowski and W. A. Sanders, J. Mat. Sci. 21 (1987), p.1345.

[14] W. E. Lee, C. H. Drummond, III, G. E. Hilmas and S: Kumar, J. Am. Ceram. Soc. 73 (12) (1981), p.3575.

[15] K. H. Jack, Processing of Nitrogen Ceramics, Mat. Sci. Res. Vol. 11 (1978), p.561.

[16] A. Tas and M. Akinc, Powder Diffraction, Vol. 7, No. 4, December (1992), p.219.

[17] F. Sigulinski, S. Bošković, Ceram. Int. 25 (1999), p.41.

[18] G. Petzow, M. Hofmann, Mat. Sci. Forum, Vols. 113-115, Copyright Trans Tech Publications, Switzerland, (1993), p.91.

[19] Mah T. I., Mazdiyashi K. S., Ruh R., J. Am. Ceram. Soc., 62 (1979), p.12.

[20] G. Ziegler, J. Heinrich, G. Wötting, J. Mater. Sci., 22 (1987), p.3041.

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