Transport in Cathode of Lithium-Ion Cells

Abstract:

Article Preview

A mathematical model for the transport in cathode of a lithium-ion cell is developed and analytical solutions to the model equations are obtained. The derived equation is tested by fitting it to published experimental discharge characteristics. Wherever possible, the values of the relevant parameters are obtained from the same literature from which the discharge characteristics were obtained. The agreement between the predicted and the experimental discharge curves are measured statistically using t-test. Since the discharge characteristics are usually plotted as voltage versus time or capacity or even state-of-discharge, hence the expression for the cell voltage has been derived.

Info:

Periodical:

Edited by:

A.K. Arof and S.A. Hashim Ali

Pages:

101-104

DOI:

10.4028/www.scientific.net/MSF.517.101

Citation:

S. A. Hashim Ali "Transport in Cathode of Lithium-Ion Cells", Materials Science Forum, Vol. 517, pp. 101-104, 2006

Online since:

June 2006

Export:

Price:

$35.00

[1] P. Georen and G. Lindbergh, Electrochim. Acta 47 (2001), p.577.

[2] J. Newman and W. Tiedemann, AIChE J., 21 (1975), p.25.

[3] J. Newman, Electrochemical Systems, Prentice Hall, Englewood Cliffs, New Jersey (1991).

[4] T. F. Fuller, M. Doyle and J. Newman, J. Electrochem. Soc., 140 (1993) p.1526.

[5] M. Doyle and J. Newman, J. Appl. Electrochem., 27 (1997), p.846.

[6] T. F. Fuller, M. Doyle and J. Newman, J. Electrochem. Soc., 141 (1994), p.1.

[7] Doyle, M. and Newman, J., J. Electrochem. Soc., 143 (1996), p.1890.

[8] R. Darling and J. Newman, J. Electrochem. Soc., 145 (1998), p.990.

[9] P. De Vidts and R. E. White, J. Electrochem. Soc., 142 (1995) p.1509.

[10] M. W. Verbrugge and B. J. Koch, J. Electrochem. Soc., 143 (1996), p.24.

[11] G. G. Botte, B. A. Johnson and R. E. White, J. Electrochem. Soc., 146 (1999), p.914.

[12] P. M. Gomadam, J. W. Weidner, R. A. Dougal and R.E. White, J. Power Sources, 110 (2002), p.267.

[13] P. Ramadass, B. Haran, R. E. White and B. N. Popov, J. Power Sources, 123 (2003), p.230.

[14] P. Arora, M. Doyle, A. S. Gozdz, R. E. White and J. Newman, J. Power Sources, 88 (2000), p.219.

In order to see related information, you need to Login.