Experimental and First-Principles Studies of the Band Alignment at the HfO2/4H-SiC (0001) Interface

Abstract:

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The electronic properties of HfO2 films on 4H-SiC were investigated to determine their suitability as high-κ dielectrics in SiC power MOS devices. The band alignment at the HfO2/4HSiC interface was determined by X-ray photoelectron spectroscopy (XPS) and supported by density functional theory (DFT) calculations. For the experimental study, HfO2 films were deposited on ntype 4H-SiC by atomic layer deposition (ALD). XPS analysis yielded valence and conduction band offsets of 1.69 eV and 0.75 eV, respectively. DFT predictions based on two monoclinic HfO2/4HSiC (0001) structures agree well with this result. The small conduction band offset suggests the potential need for further interface engineering and/or a buffer layer to minimize electron injection into the gate oxide.

Info:

Periodical:

Materials Science Forum (Volumes 527-529)

Edited by:

Robert P. Devaty, David J. Larkin and Stephen E. Saddow

Pages:

1071-1074

DOI:

10.4028/www.scientific.net/MSF.527-529.1071

Citation:

C. M. Tanner et al., "Experimental and First-Principles Studies of the Band Alignment at the HfO2/4H-SiC (0001) Interface", Materials Science Forum, Vols. 527-529, pp. 1071-1074, 2006

Online since:

October 2006

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$35.00

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