Graded Powder Composites by Freeze Drying, Electrophoretic Deposition and Sintering

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Two approaches for the fabrication of tailored powder composites with specially distributed pore-grain structure and chemical composition are investigated. Electrophoretic Deposition (EPD) followed by microwave sintering is employed to obtain functionally graded materials (FGM) by in-situ controlling the deposition bath suspension composition. Al2O3/ZrO2 and zeolite FGM are successfully synthesized using this technique. In order to fabricate an aligned porous structure, unidirectional freezing followed by freeze drying and sintering is employed. By controlling the temperature gradient during freezing of powder slurry, a unidirectional ice-ceramic structure is obtained. The frozen specimen is then subjected to freeze drying to sublimate the ice. The obtained capillary-porous ceramic specimen is consolidated by sintering. The sintering of the graded structure is modeled by the continuum theory of sintering.

Info:

Periodical:

Materials Science Forum (Volumes 534-536)

Edited by:

Duk Yong Yoon, Suk-Joong L. Kang, Kwang Yong Eun and Yong-Seog Kim

Pages:

1533-1536

Citation:

E. Olevsky and X. Wang, "Graded Powder Composites by Freeze Drying, Electrophoretic Deposition and Sintering", Materials Science Forum, Vols. 534-536, pp. 1533-1536, 2007

Online since:

January 2007

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$38.00

[1] D. K. Agrawal, Microwave processing of ceramics: A review, Current Opinion in Solid State & Mat Sci, 3: 480-485 (1998).

[2] T. Fukasawa, Z. -Y. Deng, and M. Ando , J. Am. Ceram. Soc., 85 (9), 2151 (2002).

[3] A. L. Maximenko, O. Van Der Biest, and E. A. Olevsky, Prediction of Initial Shape of Functionally Graded Ceramic Pre-Forms For Near-Net-Shape Sintering, Sci. Sintering, 35, 5-12 (2003).

DOI: https://doi.org/10.2298/sos0301005m

[4] E. Olevsky, Theory of sintering: from discrete to continuum. Invited Review, Mater. Sci. & Eng. R. Reviews, 23, 41-100 (1998) model experiment model experiment Figure 7 FEM modeling of shape change and distortion.

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