Dispersibility of Carbon Nanotubes


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Availability of a stable carbon nanotube suspension is a prerequisite for production of polymer composites with carbon nanotube as additives. In this work nanotube suspensions, which have been prepared from various nanotubes in different dispersion agents, were compared. Dispersibility of the samples was investigated by scanning electon microscopy and atomic force microscopy. Solution of a non-ionic surfactant was also used successfully as a new dispersion agent. Geometrical parameters of the carbon nanotubes were determined by using atomic force microscopy. Correlation was found between the dispersibility and the parameters of the nanotubes and relative permittivity of the different solvents.



Materials Science Forum (Volumes 537-538)

Edited by:

J. Gyulai and P.J. Szabó




T. Gábor et al., "Dispersibility of Carbon Nanotubes", Materials Science Forum, Vols. 537-538, pp. 161-168, 2007

Online since:

February 2007




[1] Yu Ren, Feng Li, Hui-Ming Cheng, Kin Liao Tension - tension fatigue behavior of unidirectional single-walled carbon nanotube reinforced epoxy composite Carbon Vol. 3 (2003), pp.2169-2179.

DOI: https://doi.org/10.1016/s0008-6223(03)00248-3

[2] Florian H. Gojny, Malte H. G. Wichmann, Bodo Fiedler, Karl Schulte Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites - A comparative study Composites Science and Technology In press.

DOI: https://doi.org/10.1557/proc-0901-ra05-40-rb05-40

[3] W. Ding, A Eitan, F. T. Fisher, X. Chen, D. A. Dikin, R. Andrews, L. C. Brinson, L. S. Schadler, R. S. Ruoff Direct observation of polymer sheathing in carbon nanotube - polycarbonate composites Nano Letters Vol. 3 (2003), pp.1593-1597.

DOI: https://doi.org/10.1021/nl0345973

[4] Petra Pötschke, Arup R. Bhattacharyya, Andreas Janke Carbon nanotube filled polycarbonate composites produced by melt mixing and their use in blends with polyethylene Carbon Vol. 42 (2004), pp.965-969.

DOI: https://doi.org/10.1016/j.carbon.2003.12.001

[5] M. Sennett, E. Welsh, J. B. Wright, W. Z. Li, J. G. Wen, Z. F. Ren Dispersion and alignment ofcarbon nanotubes in polycarbonate Applied Physics A Vol. 76 (2003), pp.111-113.

[6] R. Andrews, M. C. Weisenberger Carbon nanotube polymer composites Current Opinion in Solid State and Materials Science Vol. 8 (2004), pp.31-37.

DOI: https://doi.org/10.1016/j.cossms.2003.10.006

[7] W. K. Hsu, M. Terrones, J. P. Hare, H. Terrones, H. W. Kroto, D. R .M. Walton Electrolytic formation of carbon nanostructures Chemical Physics Letters Vol. 262 (1996), pp.161-166.

DOI: https://doi.org/10.1016/0009-2614(96)01041-x

[8] F. Lia, H. M. Cheng, Y. T. Xinga, P. H. Tanb G. Sua Purification of single-walled carbon nanotubes synthesized by the catalytic decomposition of hydrocarbons Carbon Vol. 38 (2000), p.2041-(2045).

DOI: https://doi.org/10.1016/s0008-6223(00)00061-0

[9] S. R. Mishra, H. S. Rawat, S. C. Mehendale, K. C. Rustagi, A. K. Sood, Ranjini Bandyopadhyay, A Govindaraj, C. N. R. Rao Optical limiting in single-walled carbon nanotube suspensions Chemical Physics Letters Vol. 317 (2000), pp.510-514.

DOI: https://doi.org/10.1016/s0009-2614(99)01304-4

[10] Xianming Liu, John L. Spencer, Alan B. Kaiser, W. Mike Arnold Electric-field oriented carbon nanotubes in different dielectric solvents Current Applied Physics Vol. 4 (2004), pp.125-128.

DOI: https://doi.org/10.1016/j.cap.2003.10.012

[11] J. Miklósi, P. Póczik, J. Sytchev, K. Papp, G. Kaptay, P. Nagy, E. Kálmán Atomic force microscopy investigation of electrochemically produced carbon nanotubes Applied Physics A Vol. 72 (2001), p. S189 - S192.

DOI: https://doi.org/10.1007/s003390100664

[12] Milton R. Smith Jr., Sheila W. Hedgesa, Robert LaCountb, Douglas Kernb, Naresh Shahc, Gerald P. Huffmanc, Bradley Bockrath Selective oxidation of single-walled carbon nanotubes using carbon dioxide Carbon Vol. 41 (2003), pp.1221-1230.

DOI: https://doi.org/10.1016/s0008-6223(03)00054-x

[13] Zhihang Fan, Kuang-Ting Hsiao, Suresh G. Advani Experimental investigation of dispersion during flow of multi-walled carbon nanotube/polymer suspension infibrous porous media Carbon Vol. 42 (2004), pp.871-876.

DOI: https://doi.org/10.1016/j.carbon.2004.01.067

[14] Dale W. Schaefer, Jian Zhao, Janis M. Brown, David P. Anderson, David W. Tomlin Morphology of dispersed carbonsinge-walled nanotubes Chemical Physics Letters Vol. 375 (2003), pp.369-375.

DOI: https://doi.org/10.1016/s0009-2614(03)00867-4

[15] Youngjong Kang, T. Andrew Taton Micelle-encapsuleted carbon nanotubes: A route to nanotube composites Journal of American Chemical Society Vol. 125 (2003), pp.5650-5651.

DOI: https://doi.org/10.1021/ja034082d

[16] Liping Zhao, Lian Gao Stability of multi-walled carbon nanotube dispersion with copolymer in ethanol Colloids and Surfaces A: Physicochem . Eng. Aspects Vol. 224 (2003), pp.127-134.

DOI: https://doi.org/10.1016/s0927-7757(03)00155-9

[17] Minfang Zhang, Masako Yudasakaa, Akira Koshioa and Sumio Iijima Effect of polymer and solvent on purification and cutting of single-wall carbon nanotubes Chemical Physics Letters Vol. 349 (2001), pp.25-30.

DOI: https://doi.org/10.1016/s0009-2614(01)01181-2

[18] Linqin Jiang, Lian Gao, Jing Sun Production of aqueous colloidal dispersions of carbon nanotubes Journal of Colloid and Interface Science Vol. 26O (2003), pp.89-94.

DOI: https://doi.org/10.1016/s0021-9797(02)00176-5

[19] M. F. Islam, E. Rojas, D. M. Bergey, A. T. Johnson, A. G. Yodh High weight fraction surfactant solubilization of single-wall carbon nanotubes in water Nano Letters Vol. 3 (2003), pp.269-273.

DOI: https://doi.org/10.1021/nl025924u

[20] J. M. Bonard, J. P. Salvetat, T. Stora, F. Maier, T. Stöckli, L. Forro, W. A. De Heer, A. Chátelain Purification of carbon nanotube by liquid-phase separation of a kinetically state colloidal suspension Molecular Nanostructures pp.410-413.

[21] Rajdip Bandyopadhyaya, Einat Nativ-Roth, Oren Regev, Rachel Yerushalmi-Rozen Stabilization of individual carbon nanotubes in aqueous solution Nano Letters Vol. 2 (2002), pp.25-28.

DOI: https://doi.org/10.1021/nl010065f

[22] M. Paillet, v. Joudain, P. Poncharal, J-L. Sauvajol, A Zahab, J. C. Meyer, S. Roth, N. Cordente, c. Amiens, B. Chaudret Growth and physical properties of individual single-walled carbon nanotubes Diamond and Related Materials Vol. 14 (2005).

DOI: https://doi.org/10.1016/j.diamond.2005.02.006

[23] J. Loos, A. Alexeev, N, Grossiord, C. E. Koning, O. Regev Visualiztion of single-wall carbon nanotube (SWNT) networks in conductive polystyrene nanocomposites by charge contrast imaging Ultramicroscopy Vol. 104 (2005), pp.160-167.

DOI: https://doi.org/10.1016/j.ultramic.2005.03.007

[24] Riddick, J. A., Bunger, W. B. and Sakano, T. K. Organic Solvents, Wiley-Interscience, NewYork, 4th ed. (1986).

[25] Landoldt-Börnstein Zahlenwerte und Funktionen II/6, p.618 ff (relative permittivities) (1959).