Mechanical and Thermal Properties of Ultra-High Carbon Steel Containing Aluminum
The properties of ultrahigh carbon steels (UHCS) are strongly influenced by aluminum additions. Hardness studies of quenched UHCS-Al alloys reveal that the temperature for the start of transformation increases with increases in aluminum content. It is shown that this change is a function of the atomic percent of solute and of the valence state when comparisons are made with UHCSs containing silicon and tin as solutes. The thermal expansion of UHCSs with dilute aluminum additions shows no discontinuity in the vicinity of the ferrite-austenite transformation temperature. This is the result of a three phase region of ferrite, carbides and austenite. The slope of the expansion curve is higher in the austenite range than in the ferrite range as a result of the dissolution of carbon in austenite with temperature. Processing to achieve a fine grain size in UHCS-Al alloys was principally by hot and warm working (HWW) followed by isothermal warm working (IWW). The high temperature mechanical properties of a UHCS-10Al-1.5C material show nearly Newtonian-viscous behavior at 900 to 10000C. Tensile elongations of 1200% without failure were achieved in the 1.5%C material. The high oxidation corrosion resistance of the UHCS-10Al materials is described.
T. Chandra, K. Tsuzaki, M. Militzer , C. Ravindran
C.K. Syn et al., "Mechanical and Thermal Properties of Ultra-High Carbon Steel Containing Aluminum", Materials Science Forum, Vols. 539-543, pp. 4844-4849, 2007