Grain Boundary Migration and Compensation Effect
Anisotropy of grain boundary motion in a Fe–6at.%Si alloy is represented by a spectrum of values of the activation enthalpy of migration and the pre-exponential factor, depending on the orientation of individual grain boundaries. The general plot of these values exhibits a pronounced linear interdependence called the compensation effect. It is shown that changes of these values, caused by changes of intensive variables, are thermodynamically consistent.
P. B. Prangnell and P. S. Bate
P. Lejček, "Grain Boundary Migration and Compensation Effect", Materials Science Forum, Vol. 550, pp. 387-392, 2007