Intermediates in Ring-Disc Electrode Processes

Abstract:

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In the history of electrode processes, intermediates are of extraordinary interest. In the lecture which follows, the most common types of intermediates in electrode processes are classified. Secondly, most of the methods which are available and have been used in finding intermediates are characterised. Thirdly, the principles of detection of intermediate and final products of electrode processes on the basis of kinetic information obtained by means of the rotating ring-disc electrode method are discussed. This approach is used for identification of the products of an organic electroreduction. In conclusion, it is demonstrated that the cathodic reduction of such organic compounds involves formation of stable and unstable intermediates.

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Periodical:

Edited by:

Andreas Öchsner and José Grácio

Pages:

152-163

DOI:

10.4028/www.scientific.net/MSF.553.152

Citation:

C. A.C. Sequeira "Intermediates in Ring-Disc Electrode Processes", Materials Science Forum, Vol. 553, pp. 152-163, 2007

Online since:

August 2007

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$35.00

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