Electrochemistry and Dynamic Ionography of Self-Propagating High-Temperature Synthesis (SHS)


Article Preview

The results of a new potentiometric technique for in situ diagnostics of self-propagating high-temperature synthesis (SHS) of different complex oxides are presented. This technique is based on electrochemical processes. The characteristic peaks attributed to the electric responses from cation streams of alkali, alkaline-earth and some elements of group VI are discovered and the respective routes of the corresponding chemical reactions found.



Edited by:

Dragan P. Uskoković, Slobodan K. Milonjić and Dejan I. Raković




M. V. Kuznetsov et al., "Electrochemistry and Dynamic Ionography of Self-Propagating High-Temperature Synthesis (SHS)", Materials Science Forum, Vol. 555, pp. 73-81, 2007

Online since:

September 2007




[1] A.G. Merzhanov: Russ. Chem. Bull. Vol. 46 (1997), p.1.

[2] Yu.G. Morozov: Advances in Science and Technology Vol. 29 (2000), p.913.

[3] Yu.G. Morozov, M.V. Kuznetsov and A.G. Merzhanov: Int. J. Self-Propag. High-Temp. Synth. Vol. 6 (1997), p.1.

[4] Yu.G. Morozov, A.G. Merzhanov: Electrochemistry of SHS processes, in Self-Propagating High-Temperature Synthesis of Materials, Eds. A.A. Borisov, A.G. Merzhanov and L. De Luca (Taylor & Francis, New York 2002), p.77.

[5] Yu.G. Morozov, M.V. Kuznetsov, V.A. Fedotov et al.: Diagnostics of heterogeneous combustion with condensed products of chemical reactions by dynamic ionography method, in Modern Problems of Combustion and its Applications (IV Int. School-Seminar, Minsk, Belarus 2001), p.30.

[6] M.V. Kuznetsov and Yu.G. Morozov: Mat. Sci. Forum Vol. 378-381(2001), p.563.

[7] O.E. Kashireninov and A. Fontijn: Combustion and Flames Vol. 113 (1998), p.498.

[8] M.V. Kuznetsov, S.M. Busurin, Yu.G. Morozov and I.P. Parkin: Phys. Chem. Chem. Phys. Vol. 5 (2003), p.2291.

[9] M.V. Kuznetsov, I.P. Parkin, A. Kvick, S.M. Busurin, I.V. Shishkovski and Yu.G. Morozov: Mat. Sci. Forum Vol. 518 (2006), p.181.

[10] L. Pauling: The Nature of the Chemical Bond (Cornel Univ. Press, Ithaca 1960).

[11] N.A. Vatolin and E.A. Pastukhov: Diffraction researches of high-temperature melts structure (Nauka, Мoscow 1980).

[12] T. Penkala: Zarus Krystalochemii (PWN, Warszawa 1972).

[13] V.M. Goldschmidt: Trans. Faraday Soc. Vol. 25 (1929), p.253.

[14] J. Emsley: The Elements (Clarendon Press, Oxford 1991).

[15] G.B. Bokii: Krystallokhimiya (MGU, Moscow 1960).

[16] R.D. Shannon: Acta Cryst. A Vol. 32 (1976), p.751.

[17] R.D. Shannon and C.T. Prewitt: Acta Cryst. B Vol. 25 (1969), p.925.