Iron Oxide Nanoparticles Obtained from a Fe(II) - Chitosan Polymer Film


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In this work, iron oxide nanoparticles (~5 nm) embedded in a chitosan polymer film, were synthesized. In order to obtain this nanostructured material, firstly a homogenous film of Fe(II)-chitosan was prepared. The resulting composite film has a thickness of ~140μm. Iron oxide nanoparticles were in-situ synthesized by treating the composite film with H2O2 under alkaline conditions. The morphological analysis by Transmission Electron Microscopy (TEM) shows the nanoparticles were embedded and stabilized in chitosan polymer film. The magnetic behavior was studied by magnetization measurements. The magnetization curves at room temperature showed that iron oxide nanoparticles have a superparamagnetic behavior.



Edited by:

Arturo Ponce and Darío Bueno




J. F. Luna Martínez et al., "Iron Oxide Nanoparticles Obtained from a Fe(II) - Chitosan Polymer Film", Materials Science Forum, Vol. 644, pp. 51-55, 2010

Online since:

March 2010




[1] R.F. Ziolo, E.P. Giannelis, B.A. Weinstein, M.P. O'Horo, B.N. Ganguly, V. Mehrotra, M.W. Russell and D.R. Huffman: Science Vol. 257 (1992), p.219.

[2] K. Woo, J. Hong, S. Choi, H.W. Lee, J.P. Ahn, C.S. Kim and S.W. Lee: Chem. Mater Vol. 16 (2004), p.2814.

[3] M. Hasegawa, H. Yanagihara, Y. Toyoda, E. Kita and L. Ranno: J. Magn. Magn. Mater Vol. 310 (2007), p.2283.

[4] A. Millan, F. Palacio, A. Falqui, E. Snoeck, V. Serin, A. Bhattacharjee, V. Ksenofontov, P. Gütlich and I. Gilbert: Acta. Mater Vol. 55 (2007), p.2201.

DOI: 10.1016/j.actamat.2006.11.020

[5] R.Y. Hong, H.P. Fu, D.Q. Di, Y. Zheng and D.G. Wei: Mater. Chem. Phys Vol. 108 (2008), p.132.

[6] S. Mornet, S. Vasseur, F. Grasset, and E. Duguet: J. Mater. Chem Vol. 14 (2004), p.2161.

[7] M. Arruebo, R. Fernández-Pacheco, M. Ricardo Ibarra, and J. Santamaría: Nanotoday Vol. 2 (2007), p.22.

[8] K.M. Spiers, J.D. Cashion, and K.A. Gross: Key Eng. Mater Vol. 254-256 (2004), p.213.

[9] G. Ennas, A. Musinu, G. Pic(ICCD 2000)aluga, D. Zedda, D. Gatteschi, C. Sangregorio, J.L. Stanger, G. Concas and G. Spano: Chem. Mater Vol. 10 (1998), p.495.

DOI: 10.1021/cm970400u

[10] J.R. Jeong, S.C. Shin, S.J. Lee and J.D. Kim: J. Magn. Magn. Mater Vol. 286 (2005), p.5.

[11] J.A. López Pérez, J. Mira, J. Rivas and S.W. Charles: J. Phys. Chem. B Vol. 101 (1997), p.8045.

[12] D.F. Gorozhankin, A.A. Eliseev, K.S. Napol`skii, A.V. Lukashin, A.V. Knot`ko, Y.V. Maksimov, I.P. Suzdalev, P. Görnert and Y.D. Tret'yakov: Doklady Chemistry Vol. 396 (2004), p.132.

DOI: 10.1023/b:doch.0000033730.64507.c1

[13] S. Hashimoto, T. Uwada, H. Masuhara and T. Asahi: J. Phys. Chem. C Vol. 112 (2008), p.15089.

[14] S. Sepúlveda-Guzmán, L. Lara, O. Pérez-Camacho, O. Rodríguez-Fernández, A. Olivas and R. Escudero: Polymer Vol. 48 (2007), p.720.

DOI: 10.1016/j.polymer.2006.11.004

[15] A.L.P. Fernandes, W.A. Morais, A.I. B Santos, A.M. L Araújo D.S. dos Santos, F.J. Pavinatto, O.N. Oliveira Jr., T.N.C. Dantas, M.R. Pereira and J.L.C. Fonseca: Colloid. Polym. Sci Vol. 284 (2005), p.1.

DOI: 10.1007/s00396-005-1319-0

[16] S. Rajendran, M. Sivakumar and R. Subadevi: Solid State Ionic Vol. 167 (2004), p.335.

[17] R. Matsuno, K. Yamamoto, H. Otsuka, A. Takahara: Macromolecules Vol. 37 (2004), p.2203.

[18] M.A. Garza, M.H. Hinojosa and V.A. González González: Ingenierías Vol. 9, (2006) p.14.

[19] S. Gyergyek, M. Huskic, D. Makovec and M. Drofenik: Colloids and Surfaces A: Physicochem. Eng. Aspects Vol. 317 (2008), p.49.

[20] M.D. Mukadam, S.M. Yusuf , P. Sharma and S.K. Kulshreshtha: J. Magn. Magn. Mater Vol. 272-276 (2004), p.1401.

[21] S. Si, C. Li, X. Wang, D. Yu, Q. Peng and Y. Li: Crystal Growth & Design Vol. 5 (2005), p.391.

[22] A.J. Rondinone, A.C. S Samia and Z.J. Zhang: J. Phys. Chem. B Vol. 103 (1999), p.6876.

[23] T. Osaka, T. Matsunaga, T. Nakanishi, A. Arakaki, D. Niwa and H. Iida: Anal. Bioanal. Chem Vol. 384 (2006), p.593.

DOI: 10.1007/s00216-005-0255-7

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