Design of a New Biocompatible Ti-Based Shape Memory Alloy and Its Superelastic Deformation Behaviour


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Titanium-nickel (Ti-Ni) shape memory alloys have been widely used for biomedical applications in recent years. However, it is reported that Ni is allergic and possibly carcinogenic for the human body. Therefore, it is desirable to develop new Ni-free Ti-based shape memory alloys for biomedical applications. In the present study, a new Ti-18Nb-5Mo-5Sn (wt.%) alloy, containing only biocompatible alloying elements, was designed with the aid of molecular orbital method and produced by vacuum arc melting. Both β and α″ martensitic phases were found to coexist in the alloy after ice-water quenching, indicating the martensitic transformation. The phase transformation temperatures of the Ti-18Nb-5Mo-5Sn alloy were Ms = 7.3 °C, Mf = −31.0 °C, As = 9.9 °C, and Af = 54.8 °C. Superelasticity was observed in the alloy at a temperature higher than the Af temperature. A totally recovered strain of 3.5 % was achieved for the newly designed Ti-based shape memory alloy with a pre-strain of 4 %.



Materials Science Forum (Volumes 654-656)

Main Theme:

Edited by:

Jian-Feng Nie and Allan Morton






J. Y. Xiong et al., "Design of a New Biocompatible Ti-Based Shape Memory Alloy and Its Superelastic Deformation Behaviour", Materials Science Forum, Vols. 654-656, pp. 2087-2090, 2010

Online since:

June 2010




[1] T.W. Duerig, A.R. Pelton, D. Stöckel: Biomed. Mater. Eng. Vol. 6 (1996), p.255.

[2] R. Koster, D. Vieluf, M. Kiehn, et al: The Lancet Vol. 356 (2000), p.1895.

[3] J.Y. Xiong, Y.C. Li, P.D. Hodgson, C.E. Wen: Acta Biomater. Vol. 4(2008), p. (1963).

[4] J.Y. Xiong, Y.C. Li, Y. Yamada, P.D. Hodgson, C.E. Wen: Mater. Sci. Forum, Vol. 561-565 (2007), p.1689.

[5] T. Maeshima and M. Nishida: Mater. Trans. Vol. 45 (2004), p.1096.

[6] T. Grosdidier and M.J. Philippe: Mater. Sci. Eng. A Vol. 291(2000), p.218.

[7] J.I. Kim, H.Y. Kim, H. Hosoda and S. Miyazaki: Mater. Trans. Vol. 46 (2005), p.852.

[8] M. Abdel-Hady, K. Hinoshit and M. Morinaga: Scripta Mater Vol. 55 (2006), p.477.

[9] T.W. Duerig, D.F. Richter and J. Albrecht: Scripta Metallurgica Vol. 16 (1982), p.957.

[10] ASTM Standard E9-89a (2000), American Society for Testing and Materials Philadelphia.

[11] C.M. Wayman and T.W. Duerig, in: Engineering aspects of shape memory alloys, eds. T.W. Duerig, K.N. Melton, D. Stöckel, C.M. Wayman, Butterworth-Heinemann, London (1990).

DOI: 10.1016/b978-0-7506-1009-4.50005-6

[12] W. Xu, K.B. Kim, J. Das, M. Calin and J. Eckert: Scripta Mater. Vol. 54 (2006), p. (1943).

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