Improved Corrosion Resistance of Superheater Materials in H2O Containing Environments Using Mn-Diffusion Coatings


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The oxidation resistance of ferritic-martensitic 9% chromium steels in water vapour containing atmospheres is not yet satisfactory. The chromia layer provides little protection because water vapour in the atmosphere is known to promote the formation of the volatile chromium species CrO2(OH)2. If a chromium manganese spinel is formed instead, the vapour pressure of the oxy-hydroxide is greatly reduced and evaporation can largely be avoided. Enrichment of the substrate with manganese was achieved using three different processes: using (i) a sputtering technique, (ii) electrochemical deposition both followed by a diffusion heat treatment, (iii) the pack cementation method. Uniform diffusion of manganese was obtained with all of the investigated processes. The improved oxidation behaviour of the coated samples in synthetic air with 10% water vapour at 650°C was demonstrated.



Edited by:

Toshio Maruyama, Masayuki Yoshiba, Kazuya Kurokawa, Yuuzou Kawahara and Nobuo Otsuka




D. Schmidt and M. Schütze, "Improved Corrosion Resistance of Superheater Materials in H2O Containing Environments Using Mn-Diffusion Coatings", Materials Science Forum, Vol. 696, pp. 330-335, 2011

Online since:

September 2011




[1] P.J. Ennis and W.J. Quadakkers: VGB PowerTech Vol. 8 (2001), p.87.

[2] H. -G. Oehmingen, C. Berger and H. Bretfeld, in: Korrosionsschäden in Kraftwerken, edited by Verein Deutscher Ingenieure, Düsseldorf, volume 1333 of VDI Berichte (1997), p.231.

[3] M. Schütze, M. Schorr, D. Renusch, A. Donchev and J. Vossen: Materials Research Vol. 7 (2004), p.111.

[4] H. Nickel, Y. Wouters, M. Thiele and W.J. Quadakkers: Analytical and Bioanalytical Chemistry Vol. 361 (1998), p.540.

[5] F. Dettenwanger, M. Schorr, J. Ellrich, T. Weber and M. Schütze: NACE-CORROSION 2001, Houston, TX, Paper no. 01151, NACE International (2001).

[6] Software FactSage 5. 1, GTT-Technologies, Aachen, Germany.

[7] N. Birks and F.S. Pettit: Materials Science and Engineering A Vol. 143 (1991), p.187.

[8] J. Gong and G. Zangari: Journal of The Electrochemical Society Vol. 149 (2002), p. C209.