22nd Brazilian Conference on Materials Science and Engineering

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Authors: Alexandre Fontes Melo de Carvalho, Tiago Roberto da Costa, Gilvan Pereira de Figueredo, José Antônio Barros Leal Reis Alves, Rodrigo César Santiago, Marcus Antônio de Freitas Melo, Dulce Maria de Araújo Melo
Abstract: Optimization and reduction of zeolite A synthesis costs are the focus of several studies. Attention has been given to the use of residues and natural materials rich in Si and Al, such as diatomite. Diatomite needs to be calcined above 500°C to be used, which increases processing costs. This study aimed at evaluating the use of diatomite without calcination in preparing zeolite A. Alkaline hydrothermal synthesis melting and 24 h of crystallization were carried out. The materials were characterized by XRD (X-ray powder diffraction), XRF (X-ray fluorescence), BET (N2 physisorption) and SEM (Scanning Electron Microscopy). XRD data and refinement show that the obtained material presents 99.84% crystallinity, average crystallite size of 54.92 nm, and a semi-quantitative percentage of 79% zeolite A. SiO2 and Al2O3 contents in the prepared sample proved the ratio SiO2/Al2O3 = 2. The micrographies show cubic particles and agglomerated sodalite.
Authors: Ana Gabriele Storion, Maria Gabriela Nogueira Campos, Neide Aparecida Mariano, Walter Aparecido Mariano, Sylma Carvalho Maestrelli
Abstract: Conventional processes for manufacturing porous ceramic sometimes provide bodies with low mechanical strength in addition to the high complexity or cost. This work proposes a new porous ceramic processing route: gelatinization, using as raw material clay with low plasticity, water and gelatin. The characterization of the clay was carried out and specimens of various compositions were produced by varying clay content (40, 50, 55 and 60% of solids) and keeping the water and gelatin content constant in the formulation. After cold forming the samples were fired under various conditions: initial temperature of 300 or 600 °C; maximum firing temperature of 800, 900, 1000, 1100 or 1350 °C. After firing, it was obtained the values of the water absorption, bulk density, apparent porosity, linear shrinkage and mechanical resistance. The best results were for samples fired in temperatures lower than 1100 °C and 50% and 55 % of solid content.
Authors: Alexsandra Cristina Chaves, I.V. da Silva, A.L. da Silva, G.A. Neves, Danielle Nascimento Silva Oliveira
Abstract: The ceramic industry is one of the most important productive chains of the State of Pará, generating both money and employment. Kaolin has many industrial applications and new uses are constantly surveyed. Although the extraction and processing of kaolin contribute to the economy growth, the activity also provokes serious environmental issues. Being aware of the environmental problem caused by the inadequate decomposition of kaolin residues from the beneficiation process of these minerals, which pollute and attack the environment, this paper aims the chemical, physical and mineralogical characterization of the kaolin residue from the post-treatment disposal provided by CADAM S/A company. The main oxides in the residues were SiO2 and Al2O3. In the X-ray diffraction analysis it was verified that the kaolin residue is basically formed by kaolinite and quartz, in the particle size analysis it was observed that the medium size of the particle was of 1,77 μm.
Authors: Graciele Vieira Barbosa, Sabrina Vitor Gonçalves, Creuza Kimito Caceres Kawahara, Rafael Aparecido Ciola Amoresi, Margarete Soares da Silva, Jusinei Meireles Stropa, Lincoln Carlos Silva de Oliveira, Alberto Adriano Cavalheiro
Abstract: The polycrystalline ceramic named calcium and copper titanate is a dielectric ceramic with very high dielectric constant applicable in several electronic devices. The powder form for that advanced ceramic can be synthesized through chemical route, like the Polymeric Precursor Method at relative lower temperatures the presence of alkaline earth cations harms the structural homogenization during the crystallization process. In this work, the calcium and copper titanate powder was obtained by Polymeric Precursors Method by imposing a slow thermal decomposition of polymeric precursor and several crushing steps before the calcination at 800 °C for 4 hours. The entire process was observed by thermogravimetric analysis and FTIR spectrometry, including the nitrogen adsorption-desorption isotherms and X-ray diffractometry techniques for calcined power samples. It was observed the crystallization of the cubic Im-3 Ca1/4Cu3/4TiO3 phase only starts after organics removal and full calcium carbonate elimination above 700 oC, which is followed by pore elimination and particle sintering. The chemical synthetic route used in this work shows the ability to prepare CCT powders sample with very structural homogeneity, which characteristics are required to manufacturing many electronic devices.
Authors: Creuza Kimito Caceres Kawahara, Graciele Vieira Barbosa, Igor Silva de Sá, Sabrina Vitor Gonçalves, Rafael Aparecido Ciola Amoresi, Maria Aparecida Zaghete, Margarete Soares da Silva, Alberto Adriano Cavalheiro
Abstract: Magnesium-aluminum hydrotalcites can be co-substituted with others trivalent cations, such as iron III in aluminum site, which can be a promising way to modify the properties of that synthetic adsorptive material. In the present work, hydrotalcite containing 5 mol% iron III in co-substitution to the aluminum was prepared by precipitation process and compared with no co-substituted sample along the temperature of calcination at 100 and 500 oC for 4 hours. The calcined samples were characterized by simultaneous TG/DTA, X-ray Diffraction and nitrogen adsorption-desorption techniques. The iron (III) insertion showed positive results in order to provide more stable structure against high temperatures of calcination, which was observed by lesser structural decomposition of rhombohedral hydrotalcite and a more mesoporous structure.
Authors: Igor Silva de Sá, Creuza Kimito Caceres Kawahara, Graciele Vieira Barbosa, Eliane F. de Souza, Talita Cuenca Pina Moreira Ramos, Rafael Aparecido Ciola Amoresi, Margarete Soares da Silva, Alberto Adriano Cavalheiro
Abstract: Hydrotalcite are anionic clay material presenting LDH arrangement and high porosity and specific areas, which make it a good adsorbent for pollutant species in water. Besides that, that material type can be used as catalyst or catalyst support in several industrial processes. The most common compositions is based on metallic mix hydroxide with high content of magnesium, but their adsorptive properties arise from aluminum replacement in layer structure. The present work presents the synthesis of carbonated magnesium-aluminum hydrotalcite through the precipitation method in order to investigate the co-insertion of iron (III) in aluminum site. It was found the iron (III) co-inserted samples obtained at 100 and 200 oC for 4 hours present no substantial harming in relation to the common magnesium-aluminum composition. All of the samples presented high porosity and specific area, becoming an alternative anionic adsorptive.
Authors: Vitor Polezi Pesce de Campos, Gisele Aparecida Amaral Labat, Douglas Gouvea, Guilherme Frederico Bernardo Lenz e Silva
Abstract: Unconventional shale gas reservoirs have driven the growth of the oil and gas market to a new reality: till 2035 a 26% increase in US fuel production is predicted. Thus, the hydraulic fracturing technique has been increasingly used as a resource for shale gas extraction and the consequent use of proppants. Several studies have now evaluated the use of nanostructures to produce special proppants, such as nanosensors, coatings, membranes and special fluids. This work presents the perspective of the market for oil, gas, shale, hydraulic fracturing and proppants in addition to a current development of proppants. Proppants were characterized through API RP 19C, DTA and DRX analysis. The morphology of carbon nanostructures (carbon nanotubes, carbon black and few layers’ graphite from reduced graphene oxide synthesis) produced and introduced on AM (alkali-activated metakaolin) matrix composites were evaluated using scanning transmission electron microscopy (STEM).
Authors: Cristiane Fonseca de Carvalho, Cláudio Luis de Melo-Silva, Tereza Cristina Favieri de Melo-Silva, Fábio Amaral de Araújo, Jefferson Fabricio Cardoso Lins
Abstract: The aim of this study was to analyze the flexural strength of ceramics based on yttria-stabilized zirconia (YTZP) , used in the manufacture of dental prostheses infrastructure before and after aging with cyclic fatigue in moisture. The samples were made by pre-sintered blocks of ZirkonTransluzent (Zirkonzahn GMHB) from YTZP ceramics with and without feldspathic ceramic coating, divided into groups: G1 = YTZP control; G2 = YTZP aged; G3 = YTZP + feldspathic; G4 = YTZP + aged feldspathic. The samples were submitted to a three-point bending test with a speed of 0.5 mm / min. The mean values of the flexural strength values were G1 = 645 MPa (DP ± 124), G2 = 681 MPa (DP ± 129), G3 = 904Mpa (DP ± 157) and G4 = 954Mpa (DP ± 243). The values of groups G1 and G2; G3 and G4 were statistically similar, depending on the presence or absence of coating. Cyclic stresses did not affect the flexural strength of the material
Authors: Eliana dos Santos Câmara-Pereira, Ana Emília Holanda Rolim, Isabela Cerqueira Barreto, Laise Monteiro Campos Moraes, Lilian Campos, Michelle Oliveira Mendes Carneiro de Campos, Aryon de Almeida Barbosa Junior, Alexandre Malta Rossi, Silvia Rachel de Albuquerque-Santos, Fabiana Paim Rosa
Abstract: Some biomaterials can be used to promote tissue repair process. The biological substitutes (biomaterials such as hydroxyapatite beads) can be used with some advantages and purpose of mimicking responses to on-site repair of the injured bone. The objective of this study was to evaluate the osteogenic potential of the biomaterial composed of hydroxyapatite and alginate in place of the critical defect. bioceramic samples stoichiometric hydroxyapatite was produced by the precipitation method, wet method with ion molar ratio of Ca 10 (PO 4) 6 (OH) 2, in which the Ca / P ratio was equal to 1.67. The reaction conditions were favorable to the composition of a biomaterial with crystalline phase. The synthesis of the biomaterial composed of hydroxyapatite and alginate microspheres (HAAlg5%; 200 ø 425mm) was obtained from two primary solutions with the aim of, in optimal reactive conditions, to form the precipitate. After synthesis the microspheres were implanted into the defect site. The potential effects of using HAAlg5% and the application of vibratory waves in the critical defect repair were unknown and the results described in this study are promising, considering the systemic therapy and at the site of injury. The biomaterial used promoted repair the injured tissue.

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