Solid-Phase Modification of Cement Systems by Organosilicon Polymers


Article Preview

In this paper, studies of solid-phase modification of cement systems with organosilicon polymers are presented. Modification of organosilicon polymers was carried out by co-milling clinker and polymers. The number of polymers directly related to cement particles and the features of their adsorption are studied. As demonstrated on the basis of studies of IR spectra, polyorganilsilsesquioxanes and polydiorganosiloxanes participated in chemical interaction with cement systems. Structural characteristics of cement systems (specific surface and particle size), formed during mechanochemical modification, are studied. It is shown that the mechanochemical introduction of organosilicon polymers leads to a significant increase (by 30-60%) of the resistance of cement stone to freezing-thawing in salt solutions.



Edited by:

Dr. Denis Solovev




S.V. Vavrenyuk et al., "Solid-Phase Modification of Cement Systems by Organosilicon Polymers", Materials Science Forum, Vol. 945, pp. 263-268, 2019

Online since:

February 2019




[1] Sheikin, A. E., Y. V. Chekhov, Brusser M. I. Structure and properties of cement concretes. M. Stroyizdat, (1979).

[2] Ratinov, V. B., Rosenberg ti Additive in concrete. M. Stroyizdat, (1973).

[3] Batrakov V. G. Modified concrete. Theory and practice. M. Technoproject, (1998).

[4] Vavrenyuk S. V., Orentlicher L. P., Alikovskiy A.V., Modification of cement-mineral systems by non-functional organosilicon compounds. Building materials, equipment and technologies of XXI century. 10 (2004) 48-50.

[5] Alekseev S. N., Ivanov F. M., Modra, S., Sisli P., Durability of reinforced concrete in aggressive environments. M., Stroiizdat. (1990).

[6] Kharitonov N. P. Ivanov, Y. A., Glushkov, N. E., Organosilicon compounds and materials to improve the durability of concrete. Leningrad, Nauka: Leningrad. otd-nie, (1982).

[7] Kharitonov N. P. Some theoretical aspects of obtaining a silica-organic materials. In the book Protective high temperature coatings. Leningrad: Nauka. (1972) 262-269.

[8] Kharitonov N. P. Research in the field of ORGANOMETALLIC compounds and materials based on them. In the book Problems of silicate chemistry. L. (1974) 278-294.

[9] Voronkov M. G. A Siloxane bond. Novosibirsk, Science, (1976).

[10] Vavrenyuk S. V., Avramenko V. A., Alikovskiy A.V., Majors V. Yu., Mikhailova N. H. Influence of organosilicon compounds of non-functional type on Portland cement clinker grinding. Building materials. 12 (2013) 78-80.

[11] Alikovskiy A.V., Zolotar G. Ya., Vavrenyuk S. V., Modification of cement systems by non-functional organosilicon compounds. SB. papers of the 2nd int. SIMP. Chemistry and education. Vladivostok. (2000) 84-86.

[12] Vavrenyuk S. V., Efimenko Yu. V. Features of carbonization of cement systems in the presence of organic additives. Vestnik VolgGASU. Ser.: Construction and architecture. 31 (50) (2013) 101-104.

[13] Thomas M. D. A., the effect of complementary cementing materials on alkali-silica reaction. Cement and Concrete Research. 41 (2011) 1224-1231.


[14] Voronkov M. G., Generalities reaction of the splitting of siloxane bonds. Report on nauch. works, presented. on the receipt Kazan. doctor's degree chemical. Sciences. Acad. of Sciences of the USSR. M. (1967) 78-81.

[15] Modified silica in sorption, catalysis and chromatography. Edited by Lisichkin G. V. M. Chemistry (1986).

[16] Ostrovsky V. V., Glebova I. B., Starodubtseva N. H. Kharitonov N. P., The influence of the ratio of methylphenylsiloxane units on the thermal stability of polyorganosiloxanes. In the book Research in the field of physics and chemistry of rubbers and rubber. L. (1975) 173-175.

[17] Pan J. W., Feng Y. T., Wang J. T., Sun C. Q., Zhang C. H., Owen D. R. J., Modeling of alkali-silica reaction in concrete. Frontier of Structural Civil Engineering. 6 (2012) 1-18.

[18] Rossella Pignatelli, Claudia Comi, Paulo J. M. Monteiro. A coupled mechanical and chemical damage model for concrete affected by alkali-silica reaction. Cement and Concrete Research. 53 (2013) 196-210.


[19] Ostrovsky V. V., Starodubtseva N. N., Kharitonov N. P., On the possibility of using the component parts of the IR spectra to study the solid products thermo-oxidative degradation of polymethylphenylsiloxane. IP. 4 (1975) 560-562.

[20] Silica-organic materials, their properties and application technology. Institute of silicate chemistry. L., Science. (1979).

[21] K. A. Andrianov, Khananashvili L. M., Technology of Organoelement monomers and polymers. Moscow, Khimiya. (1973).

[22] Andrianov K. A., Some modern problems of polymer science. In the book Synthesis and modification of polymers. Moscow, Nauka. (1976) 5-22.

[23] Rahman A, Singh A, Harimkar S.P., Singh R.P., Mechanical characterization of fine grained silicon carbide consolidated using polymer pyrolysis and spark plasma sintering. Ceram Int. 40 (2014) 12081-12091.


[24] Sahin FC, Apak B, Akin I, Kanbur HE, Genckan DH, Turan a, Goller G, Yucel O. Spark plasma sintering of B4C-SiC composites. Solid State SCi. 14 (2012) 1660-1663.


[25] Vavrenyuk S. V. Influence of non-functional organosilicon polymers on dispersion processes of Portland cement. Collection of scientific works basic research of RAASN on scientific support of development of architecture, urban planning and construction industry of the Russian Federation in 2012,. Volgograd, VolgGASU. (2013) 336-338.