Advanced Structural and Functional Materials for Protection, 2008

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Authors: S. Akhtar, D. Shukla, V. Kumar
Abstract: The crystallization behavior of semi-crystalline plastics plays a vital role in the development of properties of plastics. The present study examines the effect of addition of 1-5% nano talc filler particles on the nucleation behavior and crystal morphology. Differential Scanning Calorimetry was used to study the dynamic crystallization kinetics of PEEK with different loadings of nano talc filler. The crystalline morphology and non-isothermal kinetics were investigated. Crystallization behaviour was studied using Avrami equation. It is found that the addition of nano-talc enhances the rate of nucleation; however, the growth rate of the crystals reduces.
Authors: M.A. Jothi Rajan, T. Mathavan, T.S. Vivekanandam, S. Umapathy, V. Ganesan, G.S. Okram, Ajay Soni
Abstract: Polymers are prepared by various methods. The method of preparation plays an important role in deciding many of the physical properties of polymers. In this work Poly (Methyl Acrylate), PMA, is synthesized by free radical addition polymerization in the presence a monomer, an initiator under the influence of ultrasound. Methyl Acrylate (E-Merck, India) of proper strength is mixed with aqueous sodium peroxodisulphate solution of known strength and the time of passage of ultrasound is varied in steps of 30 minutes and 10 samples of solid PMA are obtained for 10 different periods of passage of ultrasound. Solid PMA samples are purified and air-dried under clean environment. TGA, DTA measurements are done on all the 10 PMA samples. The thermal stability of PMA with the change in the time of passage of ultrasound is discussed quantitatively. The thermal stability of PMA, synthesized sonochemically shows better results over the thermal method of synthesis. However in this paper we report the measurements made on PMA samples synthesized at 30 and 300 minutes sonication periods respectively.
Authors: K.R. Gopi, R. Nagarajan
Abstract: Cavitation erosion is predominant in pipelines for liquid transportation, causing damage to pipe wall, impeller and their accessories. The present study is focused on development of cavitation -wear resistant nano-ceramic particle-reinforced polymer matrix material; and on study of its feasibility to be used as lining material in hydraulic transportation. The polymer/nano composite is fabricated using power ultrasound in all three process steps: synthesis of nano-dimensional particles of white fused alumina (WFA) from micron size particles, optimized blending and finally reinforcement into poly methyl methacrylate (PMMA) matrix. The effect of ultrasonic parameters on nanocomposite/ virgin polymers (like polyethylene and polypropylene) is studied by measuring mass loss of the materials and suspension turbidity during exposure time. At low frequency (20-60 kHz), cavitation intensity is predominant; this effect is utilized for fabricating sub-micron particles, and for performing accelerated cavitation erosion tests. At high frequency, acoustic streaming is predominant; this effect is utilized for blending and reinforcing of the nano ceramic particles into polymer matrix. The size and quantity of the particles generated by cavitation erosion was analyzed by Laser Particle Size Analyzer (20 nm-1400 micron range). The nano-composite coupons were analyzed before and after the ultrasonic erosion test using SEM. It is concluded that lowfrequency sonication is a viable option for cavitaton erosion testing of ceramic/polymer composites.

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