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Synthesis and Characterization of Metal Salen Complexes Immobilized MCM-41 and their Catalytic Activity for Benzyl Alcohol Oxidation

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Abstract:

Co(Ⅱ)-, Mn(Ⅲ)- and Cu(Ⅱ)- salen type complexes were immobilized over mesoporous MCM-41 through coordinating the metal atom to amino groups covalently attached to the MCM-41 functionalized 3-aminopropyl triethoxysilane (3-APTES). The XRD patterns shown that mesostructure of MCM-41 remains intact after various modifications, while spectral techniques shown the successful anchoring the neat complexes inside MCM-41. The catalytic activity results shown that Co-salophen/MCM-41 exhibited the highest catalytic performance in the water phase selective oxidation of benzyl alcohol.

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Periodical:

Advanced Materials Research (Volumes 881-883)

Pages:

292-296

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.881-883.292

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Online since:

January 2014

Authors:

De Xuan Huang, Yi Bing Song, Yi Wen Fang, Chang Yong Sun

Keywords:

Benzyl Alcohol, MCM-41, Metal-Salen, Oxidation, Schiff Base Complex

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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