Papers by Author: Bing Lin Zhang

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Authors: Gang Chen, Hui Zhong Ma, Lan Zhang, Hong Ye Chen, Qiue Xia, Ning Yao, Bing Lin Zhang
Abstract: Three kinds of different diameter carbon nanotubes (CNTS) films deposited on aluminum sheets by electrophoretic deposition method. Scanning electron microscopy was used to observe the surface morphology of the films. The field emission properties of the films were tested by using a diode structure. The turn-on field for 8nm diameter CNTs film was 0.8V/μm and the current density of 5200μA/cm2 was obtained at 2.3V/μm. While corresponding data for 15nm and 30nm CNTs films were 1.6V/μm, 1.4V/μm, and 2200μA/cm2, 850μA/cm2 at 3.0V/μm respectively. The deposited film with 8nm diameter CNTs appeared excellent emission properties.
Authors: L.L. Fang, Bing Lin Zhang, Ning Yao
Abstract: In this paper, we report that the experimental results of fabricated diamond-metal composite film. Electrotyping method was used to deposit the thick film. During the deposition, low internal stress electrolytic solution, the electric current density of cathode, PH value, temperature, the distance between cathode and anode, the pretreatment of motherboard cathode were selected simultaneously. It was found that stirring strongly affected the quality of the film. Especially stirring velocity affected the distribution of diamond grains. Scanning electron microscope (SEM), X-ray photoemission spectroscopy (XPS) and X-ray diffraction (XRD) were used to measure the surface morphology, the crystal microstructure, diamond grains distribution and the chemical environment of the film.
Authors: Lan Zhang, Hui Zhong Ma, Ning Yao, Bing Lin Zhang
Abstract: White carbon films with sp1-hybridization of carbon were synthesized by microwave plasma chemical vapor deposition. The surface morphology of the deposited film, which consisted of nanograins and nanofibers, was observed by scanning electron microscope. The x-ray diffraction peak at 2θ=21.69o corresponds to the (110) facet of β modifications of white carbon material. The peak position at 283.2 eV in x-ray photoelectron spectrum represents binding energy of C1s core level of sp1-hybridization of carbon. Field electron emission properties of the film were tested by using a diode structure in a vacuum chamber. The turn-on field of 2.3V/μm and the emission current density of 360μA/cm2 at electric field of 7V/μm were obtained.
Authors: Hui Zhong Ma, Lan Zhang, Jun Jie Zhang, Yun Hai Du, Ning Yao, Bing Lin Zhang
Abstract: A flexible carbon thin film was prepared by laser induced when phase changing of polyimide thin film. There is no substrate for this thin film. It could be curved at any angle. The electron emission properties of the prepared thin film were measured by a diode mechanism; the thin film was used as a cathode and indium-tin-oxide (ITO) glass as an anode. The turn-on field of the thin film was about 2.1 V/µm. The current density of the thin film was about 150 µA/cm2 at the electric field of 4.5 V/µm. The electron emission measurements indicate that the thin film could be a good candidate electron emission material in flat panel display or be used as other electron source. The morphology and structure of the thin film were investigated by optical microscope and Raman spectroscopy.
Authors: Lan Zhang, Hui Zhong Ma, Xue Xiang Li, Ning Yao, Bing Lin Zhang
Abstract: Carbon nitride nanotubes (CN-NT) thin films were prepared on Ni-Cr coated glass substrate by microwave plasma enhanced chemical vapor deposition at a relatively low temperature of 600~650 °C. The morphology of the films were observed by scanning electron microscopy. The microstructure of the film were analyzed by x-ray photoelectron spectroscopy, x-ray diffraction, and Raman spectroscopy. The characteristics of field emission of CN-NT thin films were measured. Experimental results indicate that the film structure and properties of the field electron emission are related to flow ratio of N2 to CH4. When the flow ratio of N2 to CH4 was 3.3, the obtained film had a better field electron emission characteristics. The turn-on field of the film was 3.7 V/µm . The current density was 413.3 µA/cm2 at an electric field of 8 V/µm.
Authors: Zhi Qian Wang, Jin Hai Gao, Ning Yao, Bing Lin Zhang
Abstract: Chain-like Carbon Nano-tubes films have been synthesized by microwave plasma enhanced chemical vapor deposition (MWPECVD). The titanium-coated ceramic substrate was placed in a stainless steel reaction chamber of MPCVD system. Prior to deposition, The substrates were grinded with SiO2 powder with Fe dopant . The mixture gas of methane (CH4) and hydrogen (H2) was introduced into the chamber. The flow rates of CH4/H2 were controlled at 14/100 sccm by mass flower, respectively. The total pressure in the chamber was kept at 6.2kPa during the deposition. The microwave power of 1700w, worked at a frequency of 2450Mhz, was applied during deposition. The deposition time was only 1minute. The nano-structure of the deposited films was analyzed by SEM, TEM and Raman spectroscopy. The chain-like nano-tubes randomly distributed on the substrates. The nano-tubes are multi-wall with diameter of about 60 nm. The field electron emission characteristics of the Chain-like Carbon Nano-tubes films were measured under the vacuum of 10-5Pa. The low turn-on field of 0.74V/μm and emission current density of 8.5mA/cm2 at electric field 2.9V//μm were obtained. The mechanism of its field emission properties was also discussed.
Authors: Zhan Ling Lu, Chang Qing Wang, Ning Yao, Yu Jia, Bing Lin Zhang
Abstract: In this paper it had been observed experimentally that hydrogen adsorption on nano-structure sp2-bonded amorphous carbon film, which was produced on ceramic substrate by microwave plasma chemical vapor deposition system, could improve its field emission property. Considering that surface morphology is not significantly varied with hydrogen adsorption, we suggested that hydrogen adsorption on the film surface mainly lowered the work function of emitter surface. For confirmation of the above suggestion, theoretical calculation was performed to investigate work functions of graphite (0001) surfaces with different hydrogen chemisorption sites at 1/2 H coverage by using first principles method based on DFT-GGA. An asymmetric slab supercell approach with periodic boundaries had been employed to model the graphite (0 0 0 1) surface. The calculation results were in agreement with experimental conclusion.
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