Papers by Author: Qing Fu Zhao

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Authors: Shi Yuan Sun, Qing Fu Zhao, Yuan Xue
Abstract: Spinning and finishing techniques of a durable softening and water-repellent PP/HDPE heat-bondable fiber were introduced. The fiber has a core-sheath structure. PP is the core and HDPE is the sheath. The core-sheath fiber structure and spinning materials properties make the fiber have a good heat-bonding performance. During the finishing process the fiber got a durable softening and water-repellent quality by the durable waterproofing agent—a mixture of PMHS and PDMS. Experiments show that the fibers begin to melt and bond each other at 127.5°C and could keep a good water-repellent performance after being washed five circles.
Authors: Qing Fu Zhao, Shi Yuan Sun, Xiao Wei Jiang, Ming Hai Qu, Yu Zhong Wang
Abstract: Flame retardant nanocomposites were synthesized by melt-blending phosphorus-containing copolymer (PET-co-DDP) with multi-wall carbon nanotubes. PET-co-DDP was copolymerized with terephthalic acid (TPA), ethylene glycol (EG) and 9, 10-dihydro-10[2, 3-di-(hydroxy carbonyl)propyl]-10-phosphaphenanthrene-10-oxide (DDP). The structure of the nanocomposites was characterized by scan electron microscopy (SEM). Fire property measurements by cone calorimeter revealed that the incorporation of multi wall carbon nanotubes into PET-co-DDP significantly reduced the peak heat release rates compared with the PET-co-DDP. The thermal properties of the nanocomposites were investigated by thermogravimetric analysis (TGA). It was found that the thermal stability of copolyester was improved by the addition of the multi-wall carbon nanotubes. Char formation is the main factor for these improvements. The flame retardant performance was achieved through the formation of a relatively uniform network-structured floccule layer covering the entire sample surface without any cracks or gaps. This layer re-emitted much of the incident radiation back into the gas phase from its hot surface.
Authors: Qing Fu Zhao, Xiao Wei Jiang, Shi Yuan Sun, Ming Hai Qu, Yu Zhong Wang
Abstract: A new type of nanocomposite was composited by the way of copolymerization of flame-retardant monomer DDP, PET monomer, terephthalic acid and ethylene dlycol. This article mainly researched the rheology behavior of different slices such as its apparent shear rate and shear stress and the relationship of the both in the use of capillary rheometer, and at the same time, the data of viscous flow activation energy of different sample were obtained. The result shows that under the same temperature, it is the PET/10%DDP/3% BaSO4 that is the best on the mobile performance that needs less shear stress and the temperature control in need is less strict than PFRP.
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