Papers by Keyword: Self-Propagation High-Temperature Synthesis (SHS)

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Authors: Saowanee Singsarothai, Vishnu Rachpech, Sutham Niyomwas
Abstract: The steel substrate was coated by Fe-based composite using self-propagating high-temperature synthesis (SHS) reaction of reactant coating paste. The green paste was prepared by mixing precursor powders of Al, Fe2O3 and Al2O3. It was coated on the steel substrate before igniting by oxy-acetylene flame. The effect of coating paste thickness and the additives on the resulted Fe-based composite coating was studied. The composite coating was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) couple with dispersive X-ray (EDS).
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Authors: Dario Vallauri, Isabel M. Martins, Fabio A. Deorsola, Ignazio Amato, Francisco Delmas, Manuela Oliveira
560
Authors: Ling Zhen Zhang, Chun Chao Zhang
Abstract: In this paper, the SHS process was accomplished using titanium dioxide and aluminum powders as raw materials. It was found that the combustion process exhibited the self-spiral combustion mode and alumina whisker had formed. The morphology, microstructure and growth mechanism of alumina whisker were investigated.
1021
Authors: Galina Xanthopoulou
Abstract: The Self-Propagating High-Temperature Synthesis (SHS) method has been used to produce a new class of active catalyst materials based on metals, metal oxides and spinels for various applications. The method is characterized by very fast processing times (of the order of minutes), relatively low preheating temperatures and very high reaction temperatures produced as a result of carefully designed exothermic reactions. A large range of materials have been produced and characterized by a variety of physico-chemical and mechanical tests. This review devoted to Catalytic properties of SHS products. A number of catalytically active materials all over the world have been identified which offer promise for applications ranging from oxidation of CO and hydrocarbons to reduction of NOx, methane dehydrogenation and other.
287
Authors: Y. Choi
Abstract: NixZn1-xFe2O4 ferrites with initial unit molar ratio of NiO/ZnO were prepared by self-propagating high temperature synthesis (SHS) at the oxygen partial pressures of 0.25 MPa. Neutron diffraction analysis shows that final product is Ni0.38Zn0.62Fe2O4 (χ2=1.68). The combustion temperature and propagating rate were about 1180 K and 4.2 mm/sec, respectively. The ferrite particle size was less than about 350 nm. The coercive force, maximum magnetization, residual magnetization, susceptibility and curie temperature of Ni0.38Zn0.62Fe2O4 powders prepared by SHS are 2878 A/m, 6.805 Wb/m2Kg, 1.27 Wb/m2Kg , 0.042 m3/kg and 42.20 °C, respectively.
371
Authors: Kiyotaka Matsuura, Yusuke Hikichi, Masayuki Kudoh
Abstract: TiC particle dispersed FeAl intermetallic alloys have been combustion synthesized from mixtures of titanium, carbon, aluminum and iron powders. When the powder mixture was heated in an argon atmosphere to approximately 900 K, an abrupt increase in temperature was observed, which indicates that the combustion synthesis reaction occurred in the powder mixture. The combustion-synthesized alloys consisted of an FeAl matrix phase with homogeneously dispersed fine TiC particles. As the concentrations of titanium and carbon of the powder mixture increased, the volume fraction and average diameter of the TiC particles increased, and Vickers hardness of the sample also increased.
1605
Authors: I. Zlotnikov, I. Gotman, Leonid M. Klinger, Elazar Y. Gutmanas
Abstract: Dense FGMs with gradually changing fraction of very hard and light-weight B4C particles were fabricated employing an original Reactive Forging (RF) combustion synthesis method. In RF, a self-sustained reaction (thermal explosion, TE) is ignited by placing a powder blend between preheated press rams and the high temperature achieved is utilized for consolidation of the combustion product. The reported FGMs were prepared by stacking layers of highly exothermic Ti-C-Ni powder blend diluted with varying fractions of non-reacting B4C particles. Only a limited amount of B4C could be added as its diluting action reduces the overall exothermicity of the blend. In some cases, B4C particles were precoated in order to prevent their interaction with Ti during combustion. Temperature evolution in (Ti-Ni-C)-B4C powder compacts corresponding to different FGM layers was measured separately and in the stacked form. The better understanding of combustion process in B4C-diluted blends coupled with well-devised geometrical design allowed us to fabricate FGMs with high volume fractions of B4C in the surface layer.
685
Authors: Tomohiro Tanaka, Kiyotaka Matsuura, Keisuke Kojima, Munekazu Ohno
Abstract: TiC−Fe system cermets and TiC−SUS310L (TiC−SS) system cermets with fully relative density have been produced from elemental powders via self-propagating high-temperature synthesis (SHS) reaction combined with pseudo-hot isostatic pressing. X-ray diffraction (XRD) analysis showed that the SHS products consist of TiC and the binder phase of Fe or SS. Metallographic analysis revealed TiC particles of several micrometer size were homogeneously dispersed in the binder phase. Regardless of differences in the binders, both cermets have similar tendencies: their relative densities increased and their hardness and compressive strengths decreased with increases in the volume fraction of either Fe or SS. In addition, the cermets used stainless steel as the binder had twice superior corrosion resistance to those used iron and also their hardness and compressive strength showed excellent values.
1860
Authors: Rui Zhu Zhang, Jie Yang, Da Kao Yan, Zhi Meng Guo, Wan Shan Su
Abstract: Strontium Titanate synroc samples were synthesized by combustion cynthesis (CS). Sr directly took part in the synthesis process. As a result, loading content issue is basically resolved. The products were characterized by density, microhardness X-ray diffraction, and scanning electron microscopy (SEM/EDS). The leaching rate was measured by the method of PCT. The results indicate that the Sr2+-SrTiO3 compound with high density, low leach rate and high property stability and the synthesis process is feasible in technology and economy. It can be concluded that the Strontium Titanate synroc is a perfect material to immobilize HLW Keywords: Strontium Titanate, high-level radioactive waste (HLW), immobilization, self –propagating high –temperatures synthesis (SHS).
625
Authors: Rui Zhu Zhang, Yong Li, Yu Xin Zhang, Zhi Meng Guo, Wan Shan Su
Abstract: Samples of mineral-like materials based perovskite and model high-level wastes (strontium) were fabricated by the SHS-densification and tested. The results of MCC-1, XRD and SEM/EDS analysis show that the major phase is well concordant with the design. The samples were characterized by dense structure and fine chemical stability. It is a durable material with high-level waste loading and is in favor for final geological disposal.
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