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Synthesis, Characterization and Properties of Amphiphilic Copolyfluorenes

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Abstract:

One novel fluorene-based amphiphilic copolymers has been synthesized by Suzuki polycondensation (SPC) with monomer 2,7-dibromo-9,9-bis-(3,6-dioxahepyl)fluorene and 9,9-dioctylfluorene-2,7-bis-(trimethyleneboronate). The copolyfluorenes’ molecular structure is characterized by 1H and 13C NMR as well as elemental analysis. The copolyfluorenes have high molecular weight and narrow molecular weight distribution, at the same time, are found to have good solubility and thermal stabilities. The copolyfluorenes exhibit a UV-visible absorption band in the range of 389-393 nm in both toluene solution and the film state. Upon photo-excitation around the absorption maximum wavelength, their PL spectra show a maximum peaks around at 415-427 nm.

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AICAM 2005 View Preview

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Periodical:

Advanced Materials Research (Volumes 11-12)

Pages:

371-374

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.11-12.371

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Online since:

February 2006

Authors:

Ai Ying Li, Jie Yun Chang, Kai Quan Wang, Lu De Lu

Keywords:

Copolymer, Fluorescence, Polyfluorenes, Synthesis

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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