Paper Titles
Effect of Scale Microstructure on Scale Adhesion of Low Carbon Sheet Steel
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Exfoliation and Fracture Behavior of Oxide Films Formed on Titanium and Its Alloy in High Temperature Environments
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Strains in Thermally Growing Alumina Films Measured In-Situ Using Synchrotron X-Rays
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Quantitative Adhesion Energy Values of Chromia-Rich Thermal Oxides on Stainless Steels Determined by Blister and Tensile Tests
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The Effects of Steel Composition on the Oxidation Kinetics, Scale Structure, and Scale-Steel Interface Adherence of Low and Ultra-Low Carbon Steels
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Deformation and Fracture Behavior of Surface Oxide Scale on Fe-13Cr Alloy in Hot-Rolling Process
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Quantitative Adhesion Energy Values of Chromia-Rich Thermal Oxides on Stainless Steels Determined by Blister and Tensile Tests

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Abstract:

Adhesion energy values for thermal oxide scales cyclically grown at 850 and 950°C in air on ferritic and austenitic stainless steels were obtained using an inverted blister test and a tensile test working in the SEM chamber. The blister test used water pressure for debonding the metalscale interface, whereas the tensile test led to transverse compression generating scale spallation by buckling. Adhesion energy, defined by energy for interface crack propagation by unit area, was shown to be in the range 10 to 650 J.m–2 for the chromia-rich scales with thickness in the micrometer range. Ferritic grades gave less adherent scales than austenitic ones, and a great influence of titanium was evidenced, greatly increasing scale adhesion; niobium was less operative. Adhesion was well connected with nature and morphology of Ti and/or Nb-containing precipitates at the metal-scale interface.

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Periodical:

Materials Science Forum (Volumes 522-523)

Pages:

441-450

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.522-523.441

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Online since:

August 2006

Authors:

Alain Galerie, M. Dupeux, Yves Wouters, F. Toscan

Keywords:

Adhesion, Blister Test, Chromia Scale, Stainless Steel (SS), Tensile Test

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] L. Antoni and J. -M. Herbelin: Cyclic Oxidation of High Temperature Materials, M. Schütze, W.J. Quadakkers eds., IOM Communications, London, (1999), pp.187-197.

Google Scholar

[2] F. Toscan, L. Antoni, M. Dupeux and A. Galerie: Mater. High Temp., Vol. 20, 3/4, (2003), pp.297-304.

Google Scholar

[3] J. Mougin, M. Dupeux, A. Galerie and L. Antoni: Mater. Sci. Technol., Vol 18, (2002), p.12171220.

Google Scholar

[4] J. Mougin, T. Le Bihan and G. Lucazeau: J. Phys. Chem. Solids, Vol. 62, (2000), pp.553-563.

Google Scholar

[5] J. Mougin, N. Rosman, G. Lucazeau and A. Galerie: J. Raman Spectroscopy, Vol. 32, (2001), pp.739-744.

DOI: 10.1002/jrs.734

Google Scholar

[6] A. Galerie, F. Toscan, E. N'Dah, K. Przybylski, Y. Wouters and M. Dupeux: Mater. Sci. Forum, Vol. 461-464, (2004), pp.631-638.

Google Scholar

[7] F. Toscan, L. Antoni, Y. Wouters, M. Dupeux and A. Galerie: Mater. Sci. Forum, Vol. 461-464, (2004), pp.705-712.

DOI: 10.4028/www.scientific.net/msf.461-464.705

Google Scholar

[8] Values from the steel producer ARCELOR.

Google Scholar

[9] H.E. Evans: Int. Mater. Rev., Vol. 40, (1995), pp.1-40.

Google Scholar

[10] J. Mougin, M. Dupeux, L. Antoni and A. Galerie: Mater. Sci. Eng., Vol. A359, (2003), p.4451.

Google Scholar

[11] S. Chandra-Ambhorn, F. Roussel-Dherbey, F. Toscan, Y. Wouters, A. Galerie and M. Dupeux: Mater. Sci. Technol., in press.

Google Scholar

[12] A. Galerie, J. Mougin, M. Dupeux, N. Rosman and G. Lucazeau: Proc. John Stringer Symposium on High Temperature Corrosion, Indianapolis, IN, ASM International, (2003), p.138142.

Google Scholar

[13] A. Galerie, Y. Wouters, E. N'Dah, K. Przybylski, Ceramics, in press.

Google Scholar