Dispersibility of Carbon Nanotubes

Article Preview

Abstract:

Availability of a stable carbon nanotube suspension is a prerequisite for production of polymer composites with carbon nanotube as additives. In this work nanotube suspensions, which have been prepared from various nanotubes in different dispersion agents, were compared. Dispersibility of the samples was investigated by scanning electon microscopy and atomic force microscopy. Solution of a non-ionic surfactant was also used successfully as a new dispersion agent. Geometrical parameters of the carbon nanotubes were determined by using atomic force microscopy. Correlation was found between the dispersibility and the parameters of the nanotubes and relative permittivity of the different solvents.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 537-538)

Pages:

161-168

Citation:

Online since:

February 2007

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2007 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Yu Ren, Feng Li, Hui-Ming Cheng, Kin Liao Tension - tension fatigue behavior of unidirectional single-walled carbon nanotube reinforced epoxy composite Carbon Vol. 3 (2003), pp.2169-2179.

DOI: 10.1016/s0008-6223(03)00248-3

Google Scholar

[2] Florian H. Gojny, Malte H. G. Wichmann, Bodo Fiedler, Karl Schulte Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites - A comparative study Composites Science and Technology In press.

DOI: 10.1016/j.compscitech.2005.04.021

Google Scholar

[3] W. Ding, A Eitan, F. T. Fisher, X. Chen, D. A. Dikin, R. Andrews, L. C. Brinson, L. S. Schadler, R. S. Ruoff Direct observation of polymer sheathing in carbon nanotube - polycarbonate composites Nano Letters Vol. 3 (2003), pp.1593-1597.

DOI: 10.1021/nl0345973

Google Scholar

[4] Petra Pötschke, Arup R. Bhattacharyya, Andreas Janke Carbon nanotube filled polycarbonate composites produced by melt mixing and their use in blends with polyethylene Carbon Vol. 42 (2004), pp.965-969.

DOI: 10.1016/j.carbon.2003.12.001

Google Scholar

[5] M. Sennett, E. Welsh, J. B. Wright, W. Z. Li, J. G. Wen, Z. F. Ren Dispersion and alignment ofcarbon nanotubes in polycarbonate Applied Physics A Vol. 76 (2003), pp.111-113.

DOI: 10.1007/s00339-002-1449-x

Google Scholar

[6] R. Andrews, M. C. Weisenberger Carbon nanotube polymer composites Current Opinion in Solid State and Materials Science Vol. 8 (2004), pp.31-37.

DOI: 10.1016/j.cossms.2003.10.006

Google Scholar

[7] W. K. Hsu, M. Terrones, J. P. Hare, H. Terrones, H. W. Kroto, D. R .M. Walton Electrolytic formation of carbon nanostructures Chemical Physics Letters Vol. 262 (1996), pp.161-166.

DOI: 10.1016/0009-2614(96)01041-x

Google Scholar

[8] F. Lia, H. M. Cheng, Y. T. Xinga, P. H. Tanb G. Sua Purification of single-walled carbon nanotubes synthesized by the catalytic decomposition of hydrocarbons Carbon Vol. 38 (2000), p.2041-(2045).

DOI: 10.1016/s0008-6223(00)00061-0

Google Scholar

[9] S. R. Mishra, H. S. Rawat, S. C. Mehendale, K. C. Rustagi, A. K. Sood, Ranjini Bandyopadhyay, A Govindaraj, C. N. R. Rao Optical limiting in single-walled carbon nanotube suspensions Chemical Physics Letters Vol. 317 (2000), pp.510-514.

DOI: 10.1016/s0009-2614(99)01304-4

Google Scholar

[10] Xianming Liu, John L. Spencer, Alan B. Kaiser, W. Mike Arnold Electric-field oriented carbon nanotubes in different dielectric solvents Current Applied Physics Vol. 4 (2004), pp.125-128.

DOI: 10.1016/j.cap.2003.10.012

Google Scholar

[11] J. Miklósi, P. Póczik, J. Sytchev, K. Papp, G. Kaptay, P. Nagy, E. Kálmán Atomic force microscopy investigation of electrochemically produced carbon nanotubes Applied Physics A Vol. 72 (2001), p. S189 - S192.

DOI: 10.1007/s003390100664

Google Scholar

[12] Milton R. Smith Jr., Sheila W. Hedgesa, Robert LaCountb, Douglas Kernb, Naresh Shahc, Gerald P. Huffmanc, Bradley Bockrath Selective oxidation of single-walled carbon nanotubes using carbon dioxide Carbon Vol. 41 (2003), pp.1221-1230.

DOI: 10.1016/s0008-6223(03)00054-x

Google Scholar

[13] Zhihang Fan, Kuang-Ting Hsiao, Suresh G. Advani Experimental investigation of dispersion during flow of multi-walled carbon nanotube/polymer suspension infibrous porous media Carbon Vol. 42 (2004), pp.871-876.

DOI: 10.1016/j.carbon.2004.01.067

Google Scholar

[14] Dale W. Schaefer, Jian Zhao, Janis M. Brown, David P. Anderson, David W. Tomlin Morphology of dispersed carbonsinge-walled nanotubes Chemical Physics Letters Vol. 375 (2003), pp.369-375.

DOI: 10.1016/s0009-2614(03)00867-4

Google Scholar

[15] Youngjong Kang, T. Andrew Taton Micelle-encapsuleted carbon nanotubes: A route to nanotube composites Journal of American Chemical Society Vol. 125 (2003), pp.5650-5651.

DOI: 10.1021/ja034082d

Google Scholar

[16] Liping Zhao, Lian Gao Stability of multi-walled carbon nanotube dispersion with copolymer in ethanol Colloids and Surfaces A: Physicochem . Eng. Aspects Vol. 224 (2003), pp.127-134.

DOI: 10.1016/s0927-7757(03)00155-9

Google Scholar

[17] Minfang Zhang, Masako Yudasakaa, Akira Koshioa and Sumio Iijima Effect of polymer and solvent on purification and cutting of single-wall carbon nanotubes Chemical Physics Letters Vol. 349 (2001), pp.25-30.

DOI: 10.1016/s0009-2614(01)01181-2

Google Scholar

[18] Linqin Jiang, Lian Gao, Jing Sun Production of aqueous colloidal dispersions of carbon nanotubes Journal of Colloid and Interface Science Vol. 26O (2003), pp.89-94.

DOI: 10.1016/s0021-9797(02)00176-5

Google Scholar

[19] M. F. Islam, E. Rojas, D. M. Bergey, A. T. Johnson, A. G. Yodh High weight fraction surfactant solubilization of single-wall carbon nanotubes in water Nano Letters Vol. 3 (2003), pp.269-273.

DOI: 10.1021/nl025924u

Google Scholar

[20] J. M. Bonard, J. P. Salvetat, T. Stora, F. Maier, T. Stöckli, L. Forro, W. A. De Heer, A. Chátelain Purification of carbon nanotube by liquid-phase separation of a kinetically state colloidal suspension Molecular Nanostructures pp.410-413.

Google Scholar

[21] Rajdip Bandyopadhyaya, Einat Nativ-Roth, Oren Regev, Rachel Yerushalmi-Rozen Stabilization of individual carbon nanotubes in aqueous solution Nano Letters Vol. 2 (2002), pp.25-28.

DOI: 10.1021/nl010065f

Google Scholar

[22] M. Paillet, v. Joudain, P. Poncharal, J-L. Sauvajol, A Zahab, J. C. Meyer, S. Roth, N. Cordente, c. Amiens, B. Chaudret Growth and physical properties of individual single-walled carbon nanotubes Diamond and Related Materials Vol. 14 (2005).

DOI: 10.1016/j.diamond.2005.02.006

Google Scholar

[23] J. Loos, A. Alexeev, N, Grossiord, C. E. Koning, O. Regev Visualiztion of single-wall carbon nanotube (SWNT) networks in conductive polystyrene nanocomposites by charge contrast imaging Ultramicroscopy Vol. 104 (2005), pp.160-167.

DOI: 10.1016/j.ultramic.2005.03.007

Google Scholar

[24] Riddick, J. A., Bunger, W. B. and Sakano, T. K. Organic Solvents, Wiley-Interscience, NewYork, 4th ed. (1986).

Google Scholar

[25] Landoldt-Börnstein Zahlenwerte und Funktionen II/6, p.618 ff (relative permittivities) (1959).

Google Scholar