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Solid Ionic Conductors Based on Salted Chitosan - Fatty Acid Plasticizer Systems

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Abstract:

Films of chitosan polymer doped with lithium acetate dihydrate (LiOAc.2H2O) and placticized with oleic acid (OA) and palmitic acid (PA) were prepared by the solution cast technique. The film containing 40.0 wt. % LiOAc and 10.0 wt. % of OA exhibit a room temperature conductivity of ~ 10-5 S cm-1 and the film containing 41.0 wt. % LiOAc and 7.7 wt. % of PA has conductivity ~ 10-6 S cm-1. The plot of ln(sT) versus 103/T for the highest conducting samples obey an Arrhenian relationship in the temperature range between 300 and 363 K implying that the conductivity is thermally assisted. FTIR spectroscopy and XRD techniques have been used for the complexation studies. The LiNiCoO2/chitosan-LiOAc-OA/MCMB electrochemical cell could be charged to a voltage of 4.2 V.

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Periodical:

Materials Science Forum (Volumes 480-481)

Pages:

95-100

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.480-481.95

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Online since:

March 2005

Authors:

M.Z.A. Yahya, R. Puteh, A.K. Arof

Keywords:

Chitosan (CS), Ionic Conductivity, Lithium Secondary Cells, Oleic Acid, Palmitic Acid

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© 2005 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] N.M. Morni, A.K. Arof: J. Power Sources Vol. 77 (1999), p.42.

Google Scholar

[2] R. H. Y. Subban, A.K. Arof: Physica Scripta Vol. 53 (1996), p.382.

Google Scholar

[3] N.S. Mohamed, R.H.Y. Subban, A.K. Arof: J. Power Sources Vol. 56 (1995), p.153.

Google Scholar

[4] K. Okuyama, K. Noguchi, M. Kanenari, T. Egawa, K. Osawa, K. Ogawa: Carbohydrate Polymer Vol. 41 (2000), p.237.

DOI: 10.1016/s0144-8617(99)00142-3

Google Scholar

[5] Z. Zhong, Y. Kimura, M. Takahashi, H. Yamane: Polymer Vol. 41 (2000), p.899.

Google Scholar

[6] T. Suguma, M. Cook: Progress in Organic Coating Vol. 38 (2000), p.79.

Google Scholar

[7] M. Hasegawa, A. Isogai, S. Kuga, F. Onabe: Polymer Vol. 35 (1994), p.983.

Google Scholar

[8] R.A.A. Muzzarelli: Carbohydrate Polymers Vol 29 (1996), p.309.

Google Scholar

[9] B.L. Butler, P.J. Vergano, R.F. Testin, J.M. Bunn, J.L. Wiles, J. L: J. Food Science Vol. 61 (1996), p.953.

Google Scholar

[10] I.S. Arvanitoyannis, A. Nakayama, S. Aiba: Carbohydrate Polymers Vol. 37 (1998), p.371.

Google Scholar

[11] S. Kawamura: Chitin and Chitosan: The Versatile Environmentally Friendly Modern Materials (Bangi, Malaysia 1995).

Google Scholar

[12] F.M. Gray: Solid Polymer Electrolytes: Fundamentals and Technological Applications (VCH Publisher, New York 1991).

Google Scholar

[13] M.B. Armand: Polymer Electrolyte Review I (Elsevier, UK 1987).

Google Scholar

[14] A.M.M. Ali, N.S. Mohamed, A.K. Arof: J. Power Sources Vol 74 (1998), p.135.

Google Scholar

[15] A.K. Arof, N.M. Morni, M.A. Yarmo: Mater. Sci. & Eng. B Vol. 55 (1998), p.130.

Google Scholar

[16] X. Wei, D.F. Shriver: Chemistry Material Vol. 10 (1998), p.2307.

Google Scholar

[17] Z. Osman, Z.A. Ibrahim, A.K. Arof: Carbohydrate Polymers Vol. 44 (2001), p.167.

Google Scholar

[18] W.S. Gibbon, R.P. Kusy: Polymer Vol. 39 (1998), p.167.

Google Scholar

[19] K.A. Hunter, L.C. Crosbie, G.J. Miller, A.K.D. Roy: Biochem. Vol. 11 (2000), p.408.

Google Scholar

[20] P. Tandon, G. Forster, R. Neubert, S. Wartewig: J. Mol. Structure Vol. 524 (2000), p.201.

Google Scholar

[21] S.A. Hashmi, A. Kumar, K.K. Maurya, S. Chandra: J. Physics D Vol. 23 (1990), p.1307.

Google Scholar

[22] S.S. Sekhon, G. Singh, S.A. Agnihotry, S. Chandra: Solid State Ionics Vol. 80 (1995), p.37.

Google Scholar

[23] F.H. Ahmad, H. Suhaimi, S.S. Aziz, M.A. Yarmo, A. Alumuniar: Chitin Chitosan: The Versatile Environmentally Friendly Modern Materials (Penerbit UKM, Bangi 1995).

Google Scholar

[24] N. Srivastava, A. Chandra, S. Chandra: Physics Review B Vol. 52 (1995), p.225.

Google Scholar

[25] K.K. Maurya, S.A. Hashmi, S. Chandra: Solid State Ionics: Materials and Applications (World Scientific, Singapore 1992).

Google Scholar

[26] J.M.G. Cowie: Polymer Electrolyte Review I (Elsevier, UK 1987).

Google Scholar

[27] B.E. Mellander, I. Albinsson: Solid State Ionics: New Developments (World Scientific, Singapore 1996).

Google Scholar

[28] K. Sakurai, T. Maegawa, T. Takahashi: Polymer Vol. 41 (2000), p.7051.

Google Scholar

[29] M.S. Micheal, M.M.E. Jacob, S.R.S. Prabaharan: S. Radhakrishna: Solid State Ionics Vol. 98 (1997), p.167.

Google Scholar

[30] G. Pistoia, A. Antonini, D. Zane: Electrochimica Acta Vol. 41 (1996), p.2683.

Google Scholar