Paper Titles
Development of Freeform Fabrication of Metals by Three Diminsional Micro-Welding
p.189
Phase Change of Zr-Al-N and Nb-Al-N Films Prepared by Magnetron Sputtering Method
p.195
Rust Layers Formed on Weathering Steels by Long-Term Atmospheric Exposure to Industrial and Coastal Environments
p.203
Characterization and Dissolution Behavior in a Physiological Solution of Heat-Treated CaTiO3 Thin Films with Different Thicknesses
p.209
Oxidation Behavior of Mo-Si-B In Situ Composites
p.215
Electrical Property of TiO2 Thin Film Deposited by RF Sputtering
p.221
Classification of Oxidation Behavior of Disilicides
p.227
Corrosion Behavior of Pre-Treated Fe-Al Alloys in Aqueous Acid Solutions
p.233
Development of Large Area Plasma Reactor Using Multiple Low-Inductance Antenna Modules for Flat Panel Display Processing
p.239

Oxidation Behavior of Mo-Si-B In Situ Composites

Article Preview

Abstract:

Isothermal oxidation behavior of Al added Mo-Si-B in-situ composites was investigated under Ar-20%O2 and air atmosphere over the temperature range of 1073–1673 K. The Al added Mo-Si-B composites ((Mo-8.7mol%Si-17.4mol%B)-1mol%Al) were prepared by arc-melting, and homogenized at 2073 K for 24 h in an Ar-flow atmosphere. The ternary Mo-Si-B in-situ composite exhibited a rapid mass loss at the initial oxidation stage and then the passive oxidation after the substrates were sealed with borosilicate glass in the temperature range of 1173–1473 K, whereas it exhibited a rapid mass gain around 1073 K. On the other hand, the Al addition significantly improved the oxidation resistance of Mo-Si-B in-situ composites at temperatures from 1073–1573 K. These excellent oxidation resistances are considered to be due to the rapid formation of a continuous, dense scale of Al-Si-O complex oxides.

You might also be interested in these eBooks
Designing of Interfacial Structures in Advanced Materials and their Joints View Preview

Info:

Periodical:

Solid State Phenomena (Volume 127)

Pages:

215-220

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.127.215

Citation:

Cite this paper

Online since:

September 2007

Authors:

Akira Yamauchi, Kyosuke Yoshimi, Yoshihiro Murakami, Kazuya Kurokawa, Shuji Hanada

Keywords:

Borosilicate, High Temperature Oxidation, In Situ Composite, Molybdenum Silicides

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2007 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] A. K. Vasudevan and J. J. Petrovic: Mater. Sci. Eng. Vol. A155 (1992), p.1.

Google Scholar

[2] J. J. Petrovic and A. K. Vasudevan, in: High Tempareture Silicides and Refractory Alloys, edited by C. L. Briant, J. J. Petrovic, B. P. Bewlay, A. K. Vasudevan, and H. A. Lipsitt, (Mater. Res. Soc. Proc. 322, Boston, MA, 1993) p.3.

DOI: 10.1557/proc-322-3

Google Scholar

[3] C. A. Nunes, R. Sakidja, and J. H. Perepezko, in: Structural Intermetallics 1997, edited by M. V. Nathal, R. Darolia, C. T. Liu, P. L. Martin, D. B. Miracle, R. Wagner, and M. Yamaguchi, (TMS, Champion, PA, 1997) p.831.

Google Scholar

[4] M. Akinc, M. K. Meyer, M. J. Kramer, A. J. Thom, J. J. Huebsch and B. Cook: Mater. Sci. Eng. Vol. A261 (1999), p.16.

Google Scholar

[5] K. Natesan and S. C. Deevi: Intermetallics Vol. 8, (2000), p.1147.

Google Scholar

[6] M. K. Meyer and M. Akinc: J. Am. Ceram. Soc. Vol. 79 (1996), p.938.

Google Scholar

[7] F. Chu, D. J. Thoma, K. McClellan, P. Peralta, and Y. He: Intermetallics Vol. 7 (1999), p.611.

Google Scholar

[8] K. Ito, K. Ihara, K. Tanaka, M. Fujikura, and M. Yamaguchi: Intermetallics Vol. 9 (2001), p.591.

Google Scholar

[9] K. Ihara, K. Ito, K. Tanaka, and M. Yamaguchi: Mater. Sci. Eng. Vol. A329-331 (2002), p.222.

Google Scholar

[10] K. Yoshimi, S. Nakatani, T. Suda, S. Hanada, and H. Habazaki: Intermetallics Vol. 10 (2002), p.407.

DOI: 10.1016/s0966-9795(02)00013-4

Google Scholar

[11] K. Yoshimi, S. Nakatani, N. Nomura, and S. Hanada: Intermetallics Vol. 11 (2003), p.787.

Google Scholar

[12] K. Yoshimi, S. Nakatani, T. Suda, T. Haraguchi, and S. Hanada: Materia Japan Vol. 41 (2002), p.146 (in Japanese).

Google Scholar

[13] K. Yanagihara, T. Maruyama, and K. Nagata: Intermetallics Vol. 3 (1995), p.243.

Google Scholar

[14] K. Yanagihara, T. Maruyama, and K. Nagata: Intermetallics Vol. 4 (1996), p. S133.

Google Scholar